This article is an overview of some of the contemporary debates in philosophy of chemistry. We discuss the nature of chemical substances, the individuation of chemical kinds, the relationship between chemistry and physics, and the nature of the chemical bond.

Kripke has argued that definitions of units of measurements provide examples of statements that are both contingent and a priori. In this paper I argue that definitions of units of measurement are intended to be stipulations of what Kripke calls "theoretical identities": a stipulation that two terms will have the same rigid designation. Hence such a definition is both a priori and necessary. The necessity arises because such definitions appeal to natural kind properties only, which on Kripke's account are necessary.

Recent work on Natural Kind Essentialism has taken a deflationary turn. The assumptions about the grounds of essentialist truths concerning natural kinds familiar from the Kripke-Putnam framework are now considered questionable. The source of the problem, however, has not been sufficiently explicated. The paper focuses on the Twin Earth scenario, and it will be demonstrated that the essentialist principle at its core (which I call IDENT)—that necessarily, a sample of a chemical substance, A, is of the same kind as another (...) sample, B, if and only if A and B have the same microstructure—must be re-evaluated. The Twin Earth scenario also assumes the falsity of another essentialist principle (which I call INST): necessarily, there is a 1:1 correlation between (all of ) the chemical properties of a chemical substance and the microstructure of that substance. This assumption will be questioned, and it will be argued that, in fact, the best strategy for defending IDENT is to establish INST. The prospects for Natural Kind Essentialism and microstructural essentialism regarding chemical substances will be assessed with reference to recent work in the philosophy of chemistry. Finally, a weakened form of INST will be presented. (shrink)

One type of deflationism about metaphysical modality suggests that it can be analysed strictly in terms of linguistic or conceptual content and that there is nothing particularly metaphysical about modality. Scott Soames is explicitly opposed to this trend. However, a detailed study of Soames’s own account of modality reveals that it has striking similarities with the deflationary account. In this paper I will compare Soames’s account of a posteriori necessities concerning natural kinds with the deflationary one, specifically Alan Sidelle’s account, (...) and suggest that Soames’s account is vulnerable to the deflationist’s critique. Furthermore, I conjecture that both the deflationary account and Soames’s account fail to fully explicate the metaphysical content of a posteriori necessities. Although I will focus on Soames, my argument may have more general implications towards the prospects of providing a meaning-based account of metaphysical modality. (shrink)

The paper shows epistemological, methodological and ontological peculiarities of chemistry taken as a classificatory science of materials using experimental methods. Without succumbing to standard interpretations of physical science, chemical methods of experimental investigation, classification, reference, theorizing, prediction and production of new entities are developed one by one as first steps towards a philosophy of chemistry. Chemistry challenges traditional concepts of empirical object, empirical predicate, reference frame and theory, but also the distinction commonly drawn between natural science and technology. Due to (...) its many peculiarities, I propose to treat chemistry philosophically as a special type of science, apart from other sciences. (shrink)

A critique of LaPorte's views on chemical kinds, like jade and ruby, is presented. More positively, a new slant is provided on the question of whether elements are natural kinds. This is carried out by appeal to the dual nature of elements, a topic that has been debated in the philosophy of chemistry but not in the natural kinds literature. It is claimed that the abstract notion of elements, as opposed to their being simple substances, is relevant to the Kripke–Putnam (...) approach to natural kinds and to some criticisms that have been raised against it, although I do not support the K–P account. The proposed view avoids the traditional microstructuralist approach to natural kinds. The article also addresses the question of whether natural kinds concern metaphysical or epistemological considerations. Recent attempts by chemists to modify the periodic table are brought to bear on the question of classification and consequently on whether the identification of elements is interest dependent. (shrink)

The term philosophy of chemistry is here construed broadly to include some publications from the history of chemistry and chemical education. Of course this initial selection of material has inevitably been biased by the interests of the author. This bibliography supersedes that of van Brakel and Vermeeren (1981), although no attempt has been made to include every single one of their entries, especially in languages other than English. Also, readers interested particularly in articles in German may wish to consult the (...) bibliography by Dittus and Mayer which also contains some material not included here (Dittus and Mayer, 1992). The aim is to maintain an up-to-date version of this bibliography and to publish a revised version in due course. Suggestions for further inclusions should be sent to the author. (shrink)

After a brief biography of Jaap van Brakel we set out his appropriation and use of the distinction between the manifest image and the scientific image of the world. In a certain sense van Brakel gives priority to the manifest image as the ultimate source of meaning in chemical discourses. He does not take sides in the debate about nominal and real essences, twin earths and so, but presents a compromise. As an active practitioner of the chemical arts he emphasises (...) the indispensability of models as a main tool for chemical thinking. We then turn to van Brakel’s interest in forging an intercultural point of view in which philosophy of chemistry plays an important part. (shrink)

‘Water is H 2 O’ is naturally construed as an equivalence. What are the things to which the two predicates ‘is water’ and ‘is H 2 O’ apply? The equivalence presupposes that substance properties are distinguished from phase properties. A substance like water (H 2 O) exhibits various phases (solid, liquid, gas) under appropriate conditions, and a given (say liquid) phase may comprise several substances. What general features distinguish substance from phase properties? I tackle these questions on the basis of (...) an interpretation of a theorem of thermodynamics known as Gibbs' phase rule which systematically relates these two kinds of feature of matter. The interpretation develops the idea that the things substance and phase predicates apply to are quantities of matter which sustain mereological relations and operations and exploits these mereological features in distinguishing the two kinds of property. Gibbs' phase rule is a macroscopic principle applicable for macroscopic intervals of time. Bringing intervals of time into the picture calls for a more detailed consideration of the relation between macroscopic equilibria and the corresponding dynamic equilibria at the microlevel and throws into question the simple idea that quantities can always be regarded as collections of molecules. The account provides some insight into how the continuous, macroscopic conception of matter (‘gunk’) is reconciled with the discrete microscopic conception and illuminates the interpretation of substances present in mixtures. (shrink)

What are the criteria determining the individuation of chemical kinds? Recent philosophical discussion, which puts too much emphasis on microstructure, seems to presuppose a reductionist conception not motivated by the scientific facts. The present article traces the development of the traditional notion of a substance with the rise of modern chemistry from the end of the 18th century with a view to correcting this speculative distortion.

I criticize the treatment of natural kinds as some sort of object, advocated in a recent paper by Alexander Bird. The arguments he gives for regimenting an illustrative statement featuring chemical kinds in his preferred manner are not conclusive, and his criticisms of an alternative strategy involving universally quantified sentences fail. This is important because of the widespread but poorly supported assumption that expressions of natural kinds should be treated as singular referring terms.

According to microessentialism, it is necessary to resort to microstructure in order to adequately characterise chemical substances such as water. But the thesis has never been properly supported by argument. Kripke and Putnam, who originally proposed the thesis, suggest that a so-called stereotypical characterisation is not possible, whereas one in terms of microstructure is. However, the sketchy outlines given of stereotypical descriptions hardly support the impossibility claim. On the other hand, what naturally stands in contrast to microscopic description is description (...) in macroscopic terms, and macroscopic characterisations of water are certainly possible. This suffices to counter the claim that microdescriptions are necessary. Whether it counters the impossibility claim depends on whether all macroscopic descriptions are stereotypical (stereotypical descriptions presumably being macroscopic). In so far as systematic import of “stereotypical” can be determined, it would seem not. But some macroscopic characterisations have definite affinity with everyday knowledge, which presumably stands in conflict with the spirit of the impossibility claim. Since what is characterised are properties expressed by predicates like “is water”, the necessity of identity has no bearing here, and matters of interpretation pose problems for claims to the effect that science fixes the extension of “water” as ordinarily understood. (shrink)

The purpose of this article is to show that the customary understanding of epistemic progress as a kind of belief change is incomplete and that conceptual change has to be acknowledged as a crucial driving force in epistemic progress. The author’s argument for the epistemological relevance of conceptual change proceeds as follows. First, he develops an account of conceptual change that clearly distinguishes conceptual change from belief change. He then takes a closer look at two kinds of conceptual change that (...) are of special interest from an epistemological point of view. He calls them “disclosing” conceptual change and “revisionary” conceptual change. He then shows that the idea of epistemic value that demarcates the realm of epistemological inquiry applies to concepts and conceptual change. (shrink)

The general question to be considered in this paper points to the nature of the world described by chemistry: what is macro-chemical ontology like? In particular, we want to identify the ontological categories that underlie chemical discourse and chemical practice. This is not an easy task, because modern Western metaphysics was strongly modeled by theoretical physics. For this reason, we attempt to answer our question by contrasting macro-chemical ontology with the mainstream ontology of physics and of traditional metaphysics. In particular, (...) we introduce the distinction between stuff-ontology, proper of chemistry, and individual-ontology, proper of physics. These two ontologies differ from each other in the basic categories of their own structures. On this basis, we characterize individual-ontology in such a way that the features of stuff-ontology will arise by contrast with it. (shrink)

The article examines the role of natural kinds in semantic theorizing, which has largely been conducted in isolation from relevant work in science, metaphysics, and philosophy of science. We argue that the Kripke–Putnam account of natural kind terms, despite recent claims to the contrary, depends on a certain metaphysics of natural kinds; that the metaphysics usually assumed—micro-essentialism—is untenable even in a ‘placeholder’ version; and that the currently popular homeostatic property cluster theory of natural kinds is correct only to an extent (...) that fails to vindicate the Kripke–Putnam account. This undermines the metasemantics required for anti-descriptivist semantics. _1_ Introduction _2_ From Semantics to Metaphysics _3_ Metaphysics, Part I: The Demise of Micro-essentialism _3.1_ Original micro-essentialism _3.2_ Placeholder essentialism _4_ Metaphysics, Part II: Homeostatic Property Cluster Theory _5_ Prospects for Natural Kind Term Semantics. (shrink)

Häggqvist and Wikforss argued that in the case of so-called natural kind terms, semantic externalism relies on an untenable metaphysics of kinds: microessentialism. They further claimed that this metaphysics fails, for largely empirical reasons. Focussing on the case of water, Hoefer and Martí European Journal for the Philosophy of Science, 9, rejoin that suitably construed, microessentialism is correct. I argue that their defence of microessentialism fails.

It is widely held that the meaning of certain types of terms, such as natural kind terms, is individuated externalistically, in terms of the individual's external environment. Recently a more radical thesis has emerged, a thesis we dub 'a posteriori semantics.' The suggestion is that not only does a term's meaning depend on the external environment, but so does its semantics. One motivation for this is the aim to account for cases where a putative natural kind term fails to pick (...) out a natural kind: The term may have a standard externalist semantics (if it picks out a natural kind) or a more descriptivist one (if it does not). Knowing which semantics applies will therefore require detailed empirical knowledge. This move has also been employed in cases where a singular term, such as a name, fails to have a reference. We argue that a posteriori semantics is inherently implausible, since the type of semantics common terms should be given ought not to be conditional on details of chemistry or physics. A number of difficulties for the position—'metaphysical,' epistemological, and methodological—are articulated. Finally, we suggest that a posteriori semantics misconstrues the way in which semantics is empirical. (shrink)

In The Philosophy of Philosophy, Tim Williamson has offered a sophisticated account of thought experiments and of modal epistemology. More recently, he has also engaged in a variant of the so-called ‘expertise defence’ of traditional philosophical methodology. In this paper I argue that if Williamson’s account of thought experiments and of modal epistemology is right, this seriously undermines his version of the expertise defence.

This essay critically considers the issue of natural kind essentialism. More specifically, the essay critically probes the philosophical use of chemical examples to support realism about natural kinds. My simple contention is that the natural kind debate can be understood in terms of two different cultures of academic production. These two cultures will be conceptualized using Thomas Kasulis’s distinction between intimacy and integrity as cultural orientations. Acknowledging Kasulis’s contention that, “What is foreground in one culture may be background in another”, (...) it may very well be the case that philosophers writing about chemistry place chemical practice in the background, thereby adopting the orientation of integrity. Chemists and philosophers of chemistry, on the other hand, place chemical practice at the foreground of their work, thereby adopting the orientation of intimacy. Because the intimacy orientation is grounded in chemical practice, it is preferable to the integrity orientation. Understanding the natural kinds debate from this perspective highlights the fact that the misuse of chemical examples by certain philosophers is informed by an orientation of detachment from actual chemical practice. This underscores the importance of an intimate understanding of chemical practice when deploying chemical examples in the context of philosophical discussions about ontology and metaphysics. (shrink)

Many philosophers attribute extraordinary importance to the idea of natural kinds seemingly intimating that the very possibility of certain kinds of activity are ontologically beholden to the existence of kinds. Specifically, regarding chemistry, Brian Ellis intimated that the success of any plausible metaphysical essentialism depends upon its “reliance on examples from chemistry.” Ellis’s view is representative of a tradition in analytic philosophy that has utilized chemical examples as paradigmatic natural kinds. In this regard, Kripke and Putnam emerge as the architects (...) of an entrenched research program dedicated to the chemical tradition of natural kinds in analytic philosophy. The emergence of a critical body of literature by philosophers of chemistry and others has shattered the complacent reliance upon chemical examples as exemplary kinds. On the basis of this emerging critical literature, I will critically explore the way in which chemical practice and inquiry affects the natural kind debate. So, instead of the pretense that we simply carve nature at its joints, we need to become better grounded in the practice of science, and especially with regard to the debate about natural kinds in chemical practice. Consistent with this orientation, we need to make the practice turn, that is, eradicate the fantasy of logical reconstruction and become involved with the interpretative and historical challenges of understanding the nuances of practice. The point here is quite clear, metaphysical questions regarding natural kind should be imminent to scientific practice. Indeed, any legitimate metaphysics of natural kinds should be appropriately informed and grounded in practice and not operate on the basis of a priori sovereignty. I will insert this critical discussion within the analytical context of the notion of interpretive communities and make the case that philosophers should not assume that appeals to the purity of philosophy can substitute for the complexity and practical orientation of chemical practice. (shrink)

A chemical substance is instantiated in the material world by a number of quantities of such substance, placed in different locations. A change of location implies a change in the net of relationships entertained by the QCS with the region wherein it is found. This fact entails changes of the ontological status of the CS, as this is not fully determined by the inherent features of the CS and includes a relevant relational contribution. In order to demonstrate this thesis, we (...) have chosen to analyse the status of quantities of a same CS that are synchronically located in different spacetime regions: a synthetic lab, a lab where the QCS is turned into a material, an industrial plant, the market where the QCS gets a price and a dump waste where the QCS is discarded, respectively: Chemical substance Open image in new window material Open image in new window product Open image in new window goods Open image in new window wasteThe use of first-order predicate logic, mereology and locative logic allows carrying out a regimentation process that highlights the ontological commitments implied by the formal expressions through which each element of the aforementioned series can be described. The presence of relational properties discloses the systemic nature of the CS instantiated within a spacetime region. The implications of such an aspect are discussed. (shrink)

Amidst the progress being made in the various (sub-)disciplines of the behavioural and brain sciences a somewhat neglected subject is the problem of how everything fits into one world and, derivatively, how the relation between different levels of discourse should be understood and to what extent different levels, domains, approaches, or disciplines are autonomous or dependent. In this paper I critically review the most recent proposals to specify the nature of interdiscourse relations, focusing on the concept of supervenience. Ideally supervenience (...) is a relation between different discourses which has all the advantages of reduction, but without its disadvantages. I apply the more abstract considerations to two concrete cases: schizophrenia and colour. Usually an interlevel or interdiscourse relation is seen as asymmetrical: the overlaying discourse depends on the underlying discourse (and not vice versa), where the out- or un-spoken assumption is that the ultimate underlying discourse is physical. Instead I argue that scientific categories referred to in interdiscourse relations are, ultimately, dependent on common sense categories and common sense normative criteria. It is the manifest categories and common sense ideas about what is reasonable and what is right that determine the relevant categorisations at the deeper, underlying levels. I suggest that the implications of this are not merely methodological or epistemological. (shrink)

Kripke-Putnam argument for natural kind essentialism can be said to depend on placeholder essentialist intuitions. But some argue that such philosophical intuitions are merely preschooler cognitive biases which are not supported by scientific knowledge of natural kinds. Chemical substances, for instance, whether elements or compounds do not have such privileged set of underlying properties (‘same substance’ relation) which are present in all members of the kind and which provide necessary and sufficient condition for kind membership. In this paper, I argue (...) that placeholder essentialism works for at least some of the scientific natural kinds especially for the basic chemical natural kind, i.e., element. I argue that the dual sense of the element (the basic substance and the simple substance) along with microstructuralism helps explain the essence of an element not only at the abstract level but also at the more concrete level. Based on this essentialist account of element, I conclude that placeholder essentialism is not completely without merit, and it fits nicely with at least some of our scientific natural kinds. (shrink)

Chemistry is the study of the structure and transformation of matter. When Aristotle founded the field in the 4th century BCE, his conceptual grasp of the nature of matter was tailored to accommodate a relatively simple range of observable phenomena. In the 21st century, chemistry has become the largest scientific discipline, producing over half a million publications a year ranging from direct empirical investigations to substantial theoretical work. However, the specialized interest in the conceptual issues arising in chemistry, hereafter Philosophy (...) of Chemistry, is a relatively recent addition to philosophy of science. Philosophy of chemistry has two major parts. In the first, conceptual issues arising within chemistry are carefully articulated and analyzed. Such questions which are internal to chemistry include the nature of substance, atomism, the chemical bond, and synthesis. In the second, traditional topics in philosophy of science such as realism, reduction, explanation, confirmation, and modeling are taken up within the context of chemistry. (shrink)

The present paper focuses on essentialism about natural kinds as a case study in order to illustrate this more general point. Saul Kripke and Hilary Putnam famously argued that natural kinds have essences, which are discovered by science, and which determine the extensions of our natural kind terms and concepts. This line of thought has been enormously influential in philosophy, and is often taken to have been established beyond doubt. The argument for the conclusion, however, makes critical use of intuitions, (...) and I note that the intuitions are of the sort had by preschool children, and that they are traceable to a deep-seated cognitive outlook, which is often called “psychological essentialism.” Further, if we did not have such a cognitive outlook or implicit belief set—a belief set which is in fact in place by at least age 4—then we would not have the relevant philosophical intuitions. In light of this, I consider the question of whether natural kinds actually have scientifically discovered or discoverable essences, and whether these putative essences could determine the extensions of our terms and concepts as Kripke, Putnam, and many others have supposed. In fact, a number of philosophers of biology and chemistry have argued that biological and chemical kinds do not have such essences, yet these arguments—particularly in the case of chemistry—have not been assimilated by philosophers more generally. The reason for this poor assimilation is, I suggest, that the Kripke/Putnam view is just so intuitive. But this fact, I argue, is due to a deep-seated cognitive bias, rather than to any special insight into the nature of reality. (shrink)

Argumentoin, että kripkeläinen essentialistinen teoria luonnollisista lajeista ei tarjoa niille pätevää metafysiikkaa. Sen lajiyksilöinti olettaa osoitettavan sulkemalla pois muut tekijät kuin mikrofysikaaliset tai rakenteelliset, jopa fysikokemiallisten lajien tapauksessa. Esitän yleistetyn Kaksoismaa-argumentin ja ehdotan, että lewislainen vastinyksilöteoria sovellettuna luonnollisiin lajeihin selittää muiden yksilöintikriteerien empiirisen mahdollisuuden. Kaiken kaikkiaan tämä viittaa siihen, että luonnollisilla lajeilla ei ole kiinnostavaa metafyysistä asemaa.

Given the rich diversity of research fields usually ascribed to chemistry in a broad sense, the present paper tries to dig our characteristic parts of chemistry that can be conceptually distinguished from interdisciplinary, applied, and specialized subfields of chemistry, and that may be called chemistry in a very narrow sense, or 'the chemical core of chemistry'. Unlike historical, ontological, and 'anti-reductive' approaches, I use a conceptual approach together with some methodological implications that allow to develop step by step a kind (...) of cognitive architecture for chemistry, which basically contains: (1) systematic chemical knowledge on the experimental level; (2) clarification of chemical species; (3) chemical classification systems; (4) theoretical foundation through the chemical theory of structural formulas. In a succeeding paper the results will be checked for resisting physicalistic reduction. (shrink)

The paper shows epistemological, methodological and ontological peculiarities of chemistry taken as a classificatory science of materials using experimental methods. Without succumbing to standard interpretations of physical science, chemical methods of experimental investigation, classification, reference, theorizing, prediction and production of new entities are developed one by one as first steps towards a philosophy of chemistry. Chemistry challenges traditional concepts of empirical object, empirical predicate, reference frame and theory, but also the distinction commonly drawn between natural science and technology. Due to (...) its many peculiarities, I propose to treat chemistry philosophically as a special type of science, apart from other sciences. (shrink)

Tässä artikkelissa käsittelen Descartesin ikuisten totuuksien välttämättömyyteen liittyvää ongelmaa. Teoksessa Mietiskelyjä ensimmäisestä filosofiasta (1641–1642) Descartes nostaa esiin käsitteen ikuisista totuuksista, käyttäen esimerkkinään kolmiota. Kolmion muuttumattomaan ja ikuiseen luontoon kuuluu esimerkiksi, että sen kolme kulmaa ovat yhteenlaskettuna 180°. Se on totta kolmiosta, vaikka yhtään yksittäistä kolmiota ei olisi koskaan ollutkaan olemassa. Eräät ajattelemieni asioiden piirteet ovat siis Descartesin mukaan ajattelustani riippumattomia. Ikuisia totuuksia ovat ainakin matemaattiset ja geometriset tosiseikat sekä ristiriidan laki. Samoin Descartesin kuuluisa lause “ajattelen, siis olen” lukeutuu ikuisten totuuksien (...) joukkoon. Descartesin ikuiset totuudet olisivatkin siis loogisesti välttämättömiä. Niillä on kyseinen olemus riippumatta ulkoisten kohteiden olemassaolosta tai siitä, ajattelenko niitä lainkaan. Kuitenkin kirjeenvaihdossaan Descartes pitää itsepintaisesti kiinni käsityksestään, että ikuiset totuudet ovat Jumalan vapaasti luomia ja Jumala olisi voinut luoda ne erilailla. Näin ollen luodut ikuiset totuudet eivät tarkkaan ottaen olisikaan välttämättömiä vaan kontingentteja. Ne voisivat olla myös toisella tavalla. Artikkelin alkuun esittelen Descartesin modaalista metafysiikkaa sekä luotujen ikuisten totuuksien kontingenttiudesta seuraavia tulkinnallisia vaikeuksia. Tämän jälkeen pureudun kolmeen erilaiseen ratkaisuyritykseen kommentaarikirjallisuudessa (Frankfurt 1977; Curley 1984 & Bennett 1994) ja osoitan, miksi ne eivät riitä vastaamaan ongelmaan. Lopussa vedän johtopäätöksiä ja luonnostelen mahdollisen ratkaisun. (shrink)

Title in English: "Empirical elements in modal epistemology". This article examines Peter van Inwagen's modal scepticism and argues that although van Inwagen is correct to criticise modal rationalism, there are tools in modal empiricism that are promising sources of modal knowledge.