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Green Chemistry: An Innovative Technology

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Abstract

The drive towards clean technology in the chemical industry with an increasing emphasis on the reduction of waste at source requires a level of innovation and new technology that the chemical industry is beginning to adopt. The green chemistry revolution provides an enormous number of opportunities to discover and apply new synthetic approaches using alternative feedstocks; ecofriendly reaction conditions, energy minimizations and the design of less toxic and inherently safer chemicals. In this review exciting opportunities and some successful examples of green chemistry in practice are described. While developments in the 20th century have brought various social and economic benefits to the people but these changes have also caused a range of environmental problems at both local and global levels. Over recent years, sustainable development has been accepted by government, industry and the public as a necessary goal for achieving social, economic and environmental objectives (Uark, 1999). Within this, green chemistry (www.chemsoc.org/gen) plays a key role in maintaining and improving quality of our life and preserving natural environments. The term ‘Green Chemistry’ was first coined by the US Environmental Protection Agency (EPA) in the early 1990s and major interest in green chemistry in the US began in earnest with the passage of the ‘Pollution Prevention Act’ of 1990. Thus Green Chemistry becoming a formal focus of the EPA in 1991.

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References

  • InstitutionalAuthorNameACS Green Chemistry Initiatives Get Boost from EPA Grant (1998) Chem. Eng. News. 76 IssueID33 47

    Google Scholar 

  • V.K. Ahluwalia M. Kidwai (2003) New Trends in Green Chemistry Kluwer Academic Publishers Norwell MA

    Google Scholar 

  • An Editorial by then ACS President R. Breslow. Chem. Eng. News, 74 (August 26): 72, 1996.

  • P. Anastas and J.C. Warner. Green Chemistry, Theory and Practice. Oxford University Press, 1998.

  • M.C. Cann and M.E. Connelly. Real World Cases in Green Chemistry, Am. Chem. Soc., 2001.

  • Chemical Educators Grapple with Environmental Focus for Undergraduates. Chem. Eng. News. 72 (April 4): 34–36, 1994.

  • C.S. Chen C.J. Sih (1989) ArticleTitleGeneral Aspects and Optimization of Enantioselective Biocatalysis in Organic Solvents Angew. Chem. Int. Edn. 28 695–707

    Google Scholar 

  • J.H. Clark (1999) ArticleTitleGreen Chemistry: Challenges and Opportunities Green Chem. 1 1 Occurrence Handle10.1039/a807961g

    Article  Google Scholar 

  • Clean Technology for the Manufacture of Speciality Chemicals, In W. Hoyle and M. Lancaster (Eds.), Royal Society of Chemistry, 2001.

  • T. Collins (1995) J. Chem. Edu. 72 965 Occurrence Handle10.1021/ed072p965

    Article  Google Scholar 

  • A. Corma (1995) ArticleTitleInorganic Solid Acids and their Use in Acid Catalyzed Hydrocarbon Reactions Chem. Review 95 559–614

    Google Scholar 

  • M. Csiba J. Cleophax A. Loupy J. Malthete S.D. Gero (1993) ArticleTitleLiquid Crystalline 5, 6-O-Acetals of l-Galactono-1,4-Lactone prepared by a Microwave Irradiation on Montmorillonite Tetrahedron Lett. 34 1787–1790 Occurrence Handle10.1016/S0040-4039(00)60779-7

    Article  Google Scholar 

  • S.C. DeVito and R.L. Garrett. Designing Safer Chemicals: Green Chemistry and Pollution Prevention. Am. Chem. Soc. 1996.

  • K.M. Draths J.W. Frost (1994) ArticleTitleEnvironmentally Compatible Synthesis of Adipic Acid from D-Glucose J. Amn Chem. Soc. 116 399–400

    Google Scholar 

  • K.M. Draths J.W. Frost (1995) ArticleTitleEnvironmentally Compatible Synthesis of Catechol from D-Glucose J. Amn Chem. Soc. 117 2395–2400

    Google Scholar 

  • C.A. Eckert, R. Glaeser and J.S. Brown. Tuning of Chemical Reactions with Expanded Solids. Proceeding of the fifth conference of supercritical fluids and their applications, Verona, Italy, 1999.

  • J.W. Frost K.M. Draths (1995) ArticleTitleSweetening Chemical Manufacture Chem. Britain 31 IssueID3 206–210

    Google Scholar 

  • Green Chemistry Network: www.chemsoc.org/gen. http://www.epa.gov/opptintr/greenchemistry/presgcc.htm.

  • D.C. Humber, S.B. Laing and G.G. Weingarten. U.S. 4284767, 1981, Chem. Abs. 93: 46694, 1980.

  • J.B. Jones (1986) ArticleTitleEnzymes in Organic Synthesis Tetrahedron 42 3351–3403

    Google Scholar 

  • Khurana J.M. Sonochemistry. Chem Edu. 24–29, 1990.

  • M. Kidwai (2001) ArticleTitleDry Media Reactions Pure Appl. Chem. 73 IssueID4 147–151

    Google Scholar 

  • M. Kidwai R. Mohan (2003) ArticleTitleSynthesis of 2,5-Disubstituted-1,3,4-Oxadiazoles using Dry Media Org. Prep. Proc. Int. 35 IssueID4 426–429 Occurrence Handle10.1080/00304940309355855

    Article  Google Scholar 

  • M. Kidwai R. Mohan S. Saxena (2003) ArticleTitleSolid-Supported Hantzsch-Biginelli Reaction for Syntheses of Pyrimidine Derivatives Russ. Chem. Bull. Int. Ed. 52 IssueID11 2457–2460 Occurrence Handle10.1023/B:RUCB.0000012370.16259.4f

    Article  Google Scholar 

  • M. Kidwai S. Saxena R. Mohan R. Venkataramanan (2002) ArticleTitleNovel One Pot Synthesis of Nitrogen Containing Heterocycles: Alternate Methodology to the Biginelli and Hantzsch Reaction J. Chem. Soc. Perkin Trans. 1 IssueID16 1845–1846

    Google Scholar 

  • M. Kidwai R. Venkataramanan B. Dave (2002) ArticleTitlePotassium Carbonate, a Support for the Green Synthesis of Azoles and Diazines J. Heterocyclic Chem. 39 1045–1047 Occurrence Handle10.1002/jhet.5570390530

    Article  Google Scholar 

  • M. Kidwai R. Venkataramanan B. Dave (2001) ArticleTitleSolventless Synthesis of Thiohydantoins over K2CO3 Green Chem. 3 278–279 Occurrence Handle10.1039/b106034c

    Article  Google Scholar 

  • M. Lancaster (2000) ArticleTitleGreen Chemistry Edu. Chem. 37 IssueID2 40–46

    Google Scholar 

  • J.O. Metzger (1998) ArticleTitleSolvent-free Organic Syntheses Angew. Chem. Int. Edn. 37 2975–2978

    Google Scholar 

  • R.D. Rogers, S.K. Spear, J.G. Huddeston, A.E. Visser, R.P. Swalloski and W.M. Reichert. Green Chemistry and Ionic Liquids : Synergies and Ironies. CHEMRAWN XIV, Colorado, June 10th–16th, 2001.

  • R.A. Shelden. Organic Synthesis – Past, Present and Future. Chem. Ind. (London), December. 903–906, 1992.

  • R.A. Sheldon. Catalysis and pollution prevention, Chem. Ind. 12–15, 1997.

  • B.M. Trost (1991) ArticleTitleThe Atom Economy – A Search for Synthetic Efficiency Science 254 1471–1477

    Google Scholar 

  • B.M. Trost (1995) ArticleTitleAtom Economy – A Challenge for Organic Synthesis: Homogeneous Catalysis Leads the Way Angewandte Chemie Int. Edn. 34 259–281

    Google Scholar 

  • B.M. Trost (1983) ArticleTitleSelectivity : A Key to Synthetic Efficiency Science 219 245–250

    Google Scholar 

  • B.M. Trost. A search for Atom Economy, Green Chemistry Series No. 1, Collection of Lectures: Summer schools on Green Chemistry. In P. Tundo (Ed.), Venice, 1998–2000.

  • B.M. Trost J.A. Flygare (1994) ArticleTitleA Practical Synthesis of Rosefuran. Furans from Acetylenes and Allyl Alcohols J. Org. Chem. 59 1078–1082

    Google Scholar 

  • B.M. Trost F.D. Toste H. Shen (2000) ArticleTitleRuthenium-Catalyzed Intramolecular [5+2] Cycloadditions J. Amn Chem. Soc. 22 2379–2380

    Google Scholar 

  • F. Trotta P. Tundo G. Moraglio (1987) ArticleTitleSelective Mono-N-alkylation of Aromatic Amines by Dialkyl Carbonate under Gas-Liquid Phase Transfer Catalysis (GL-PTC) Conditions J. Org. Chem. 52 1300–1304 Occurrence Handle10.1021/jo00383a024

    Article  Google Scholar 

  • P. Tundo F. Trost G. Moraglio (1989) ArticleTitleSelective and Continuous – Flow Mono-methylation of Arylacetonitriles with Dimethyl Carbonate under Gas–Liquid Phase-Transfer Catalysis Conditions J. Chem. Soc. Perkin Trans. 1 1070–1071

    Google Scholar 

  • US Environmental Protection Agency web-site www.epa.gov/opptintr/ greenchemistry/educat.htm.

  • R.S. Varma (1999) ArticleTitleSolvent-free Organic Synthesis: Using supported reagents and microwave irradiation Green Chem. 1 43–55

    Google Scholar 

  • R.S. Varma R.K. Saini R. Dhaiya (1997) ArticleTitleActive Manganese Dioxide on Silica: Oxidation of Alcohols under Solvent-free conditions using Microwaves Tetrahedron Lett. 38 7823–7824

    Google Scholar 

  • D. Villemin B. Martin (1995) ArticleTitleDry Condensation of Creatinine with aldehydes under focused Microwave Irradiation Syn. Commun. 25 3135–3140

    Google Scholar 

  • Waldman T.E. and Riley D.P. Isocyanates from Primary Amines and Carbon Dioxide : Dehydration of Carbamate Anions. J. Chem. Soc. Chem. Commun. 957–958, 1994.

  • G. Welsh. The Development and Commercial Implementation of 100% Carbon Dioxide as an Environmentally friendly Blowing Agent for the Polystyrene Foam Sheet Packaging Market, a proposal submitted to the Presidential Green Chemistry Challenge Awards Program, 1996. Website at www.epa.gov/ greenchemistry.

  • S.L. Wilkinson (1997) ArticleTitle“Green” is Practical, Even Profitable. No longer a luxury, Green Chemistry becomes a central strategy for sustainable firms Chem. Eng. News 75 IssueIDAugust 4 35–43

    Google Scholar 

  • J.S. Yadav B.V.S. Reddy K.B. Reddy K.S. Raj A.R. Prasad (2000) ArticleTitleUltrasound-accelerated synthesis of 3,4-dihydropyrimidin-2 (1H)-ones with ceric ammonium nitrate J. Chem. Soc. Perkin Trans. 1 1939–1941

    Google Scholar 

  • Zahalka H.A. and Sasson Y. One-pot conversion of Primary Alkyl Chlorides and Dichlorides into Alcohols, Diols and Ethers via Formic Ester Intermediate under Phase Transfer Conditions. Synthesis 763–765, 1986.

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  1. Department of Chemistry, University of Delhi, Delhi, 110007, India

    M. Kidwai & R. Mohan

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  1. M. Kidwai
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  2. R. Mohan
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Correspondence to M. Kidwai.

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Kidwai, M., Mohan, R. Green Chemistry: An Innovative Technology. Found Chem 7, 269–287 (2005). https://doi.org/10.1007/s10698-004-2783-1

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