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Abstract Members of the Ba2Zn1-xCdxTa2O9 (0 =< x =< 1) series have been synthesized by solid state reactions at 1473 K. Powder x-ray diffraction studies show a cubic perovskite cell with a ~ 4.1 a which increases with increase in x. Electron diffraction studies show the presence of hexagonal ordered perovskite structure in addition to the cubic structure seen by x-rays, the x = 0.5 composition showing more ordered crystallites. These samples show high dielectric constants with a maximum (r = 30 at 1 kHz) for the x = 0.5 member. The dielectric loss increases with increase in x at all the frequencies under study.
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