Off-campus access
Using PhilPapers from home?
Click here to configure this browser for off-campus access.
- Domenico Giulini, On the Statistical Viewpoint Concerning the 2nd Law of Thermodynamics - OR - a Reminder on the Ehrenfests' Urm Model.In statistical thermodynamics the 2nd law is properly spelled out in terms of conditioned probabilities. As such it makes the statement, that `entropy increases with time' without preferring a time direction. In this paper we try to explain this statement---which is well known since the time of the Ehrenfests---in some detail within a systematic Bayesian approach.
Similar books and articles
Or better: time asymmetry in thermodynamics. Better still: time asymmetry in thermodynamic phenomena. “Time in thermodynamics” misleadingly suggests that thermodynamics will tell us about the fundamental nature of time. But we don’t think that thermodynamics is a fundamental theory. It is a theory of macroscopic behavior, often called a “phenomenological science.” And to the extent that physics can tell us about the fundamental features of the world, including such things as the nature of time, we generally think that only fundamental physics can. On its own, a science like thermodynamics won’t be able to tell us about time per se. But the theory will have much to say about everyday processes that occur in time; and in particular, the apparent asymmetry of those processes. The pressing question of time in the context of thermodynamics is about the asymmetry of things in time, not the asymmetry of time, to paraphrase Price ( , ). I use the title anyway, to underscore what is, to my mind, the centrality of thermodynamics to any discussion of the nature of time and our experience in it. The two issues—the temporal features of processes in time, and the intrinsic structure of time itself—are related. Indeed, it is in part this relation that makes the question of time asymmetry in thermodynamics so interesting. This, plus the fact that thermodynamics describes a surprisingly wide range of our ordinary experience. We’ll return to this. First, we need to get the question of time asymmetry in thermodynamics out on the table.
This paper investigates what the source of time-asymmetry is in thermodynamics, and comments on the question whether a time-symmetric formulation of the Second Law is possible.
This paper investigates what the source of time asymmetry is in thermodynamics, and comments on the question whether a time-symmetric formulation of the Second Law is possible.
This paper considers the problem of causal explanation in classical and statistical thermodynamics. It is argued that the irreversibility of macroscopic processes is explained in both formulations of thermodynamics in a teleological way that appeals to entropic or probabilistic consequences rather than to efficient-causal, antecedental conditions. This explanatory structure of thermodynamics is not taken to imply a teleological orientation to macroscopic processes themselves, but to reflect simply the epistemological limitations of this science, wherein consequences of heat-work asymmetries are either macroscopically measurable (entropy) or calculable (probabilities), while efficient-causal relationships are obscure or indeterminable.
Black holes have their own thermodynamics including notions of entropy and temperature and versions of the three laws. After a light introduction to black hole physics, I recollect how black hole thermodynamics evolved in the 1970s, while at the same time stressing conceptual points which were given little thought at that time, such as why the entropy should be linear in the black hole's surface area. I also review a variety of attempts made over the years to provide a statistical mechanics for black hole thermodynamics. Finally, I discuss the origin of the information bounds for ordinary systems that have arisen as applications of black hole thermodynamics.
According to a standard view of the second law of thermodynamics, our belief in the second law can be justified by pointing out that low entropy macrostates are less probable than high entropy macrostates, and then noting that a system in an improbable state will tend to evolve toward a more probable state. I would like to argue that this justification of the second law of thermodynamics is fundamentally flawed, and will show that some puzzles sometimes associated with the second law are merely artifacts of this incorrect justification.
No categories
The purpose of this AV Column is to describe a physical paradox involving what seems to be an loophole in a well established physical law, the famous Second Law of Thermodynamics. The 2nd Law states that the amount of disorder (entropy) always either increases or remains constant for any isolated system of particles, whether they are gas molecules or light photons. An yet, as we will see, laser physicists seem to have provided us with a way of making the 2nd Law work backwards for a system of photons, so that the disorder decreases.
No categories
Statistical mechanics attempts to explain the behaviour of macroscopic physical systems in terms of the mechanical properties of their constituents. Although it is one of the fundamental theories of physics, it has received little attention from philosophers of science. Nevertheless, it raises philosophical questions of fundamental importance on the nature of time, chance and reduction. Most philosophical issues in this domain relate to the question of the reduction of thermodynamics to statistical mechanics. This book addresses issues inherent in this reduction: the time-asymmetry of thermodynamics and its absence in statistical mechanics; the role and essential nature of chance and probability in this reduction when thermodynamics is non-probabilistic; and how, if at all, the reduction is possible. Compiling contributions on current research by experts in the field, this is an invaluable survey of the philosophy of statistical mechanics for academic researchers and graduate students interested in the foundations of physics.
Consider a gas that is adiabatically isolated from its environment and confined to the left half of a container. Then remove the wall separating the two parts. The gas will immediately start spreading and soon be evenly distributed over the entire available space. The gas has approached equilibrium. Thermodynamics (TD) characterizes this process in terms of an increase of thermodynamic entropy, which attains its maximum value at equilibrium. The second law of thermodynamics captures the irreversibility of this process by positing that in an isolated system such as the gas entropy cannot decrease. The aim of statistical mechanics (SM) is to explain the behavior of the gas and, in particular, its conformity with the second law in terms of the dynamical laws governing the individual molecules of which the gas is made up. In what follows these laws are assumed to be the ones of Hamiltonian classical mechanics. We should not, however, ask for an explanation of the second law literally construed. This law is a universal law and as such cannot be explained by a statistical theory. But this is not a problem because we..
I discuss the statistical mechanics of gravitating systems and in particular its cosmological implications, and argue that many conventional views on this subject in the foundations of statistical mechanics embody significant confusion; I attempt to provide a clearer and more accurate account. In particular, I observe that (i) the role of gravity in entropy calculations must be distinguished from the entropy of gravity, that (ii) although gravitational collapse is entropy-increasing, this is not usually because the collapsing matter itself increases in entropy, and that (iii) the Second Law of thermodynamics does not owe its validity to the statistical mechanics of gravitational collapse.
Discussion of Domenico Giulini, On the statistical viewpoint concerning the 2nd law of thermodynamics - OR - a reminder on the ehrenfests' urm model
|
|
There are no threads in this forum |
Nothing in this forum yet.

