Online research in philosophy

Statistical mechanics attempts to explain the behaviour of macroscopic physical systems in terms of the mechanical properties of their constituents. Although it is one of the fundamental theories of physics, it has received little attention from philosophers of science. Nevertheless, it raises philosophical questions of fundamental importance on the nature of time, chance and reduction. Most philosophical issues in this domain relate to the question of the reduction of thermodynamics to statistical mechanics. This book addresses issues inherent in this reduction: the time-asymmetry of thermodynamics and its absence in statistical mechanics; the role and essential nature of chance and probability in this reduction when thermodynamics is non-probabilistic; and how, if at all, the reduction is possible. Compiling contributions on current research by experts in the field, this is an invaluable survey of the philosophy of statistical mechanics for academic researchers and graduate students interested in the foundations of physics.

In my master's thesis for physics and philosophy, I take a long and hard look at the debates surrounding Maxwell's Demon and the status of the second law of thermodynamics. I try to clarify the use of Maxwell's thought experiment in understanding the second law; to prove that the second law is contingent, given only classical mechanics and time asymmetry; to argue that the law only holds because of facts about the kinds of particles that exist in our universe; to show that and why the attempts to banish the demon using fluctuations, measurements or information or erasure have been unsuccessful; and I conclude that Maxwell's Demon is alive and kicking.

Despite over one-hundred years of effort, the origin of temporal asymmetry in the physical world still eludes us. While much has been learned about the role played by fundamental instabilities in microdynamics, by the imperfect isolation of systems and by cosmological facts in the origin of the behavior described by kinetic theory and thermodynamics, important puzzles still remain which continue to make the origins of asymmetric thermal behavior out of dynamically time symmetric underlying laws mysterious to us.

In statistical thermodynamics the 2nd law is properly spelled out in terms of conditioned probabilities. As such it makes the statement, that `entropy increases with time' without preferring a time direction. In this paper we try to explain this statement---which is well known since the time of the Ehrenfests---in some detail within a systematic Bayesian approach.

Huw Price argues that there are two conceptions of the puzzle of the time-asymmetry of thermodynamics. He thinks this puzzle has remained unsolved for so long partly due to a misunderstanding about which of these conceptions is the right one and what form a solution ought to take. I argue that it is Price's understanding of the problem which is mistaken. Further, it is on the basis of this and other misunderstandings that he disparages a type of account which does, in fact, hold promise of a solution.

The aim of this article is to analyse the relation between the second law of thermodynamics and the so-called arrow of time. For this purpose, a number of different aspects in this arrow of time are distinguished, in particular those of time-reversal (non-)invariance and of (ir)reversibility. Next I review versions of the second law in the work of Carnot, Clausius, Kelvin, Planck, Gibbs, Caratheodory and Lieb and Yngvason, and investigate their connection with these aspects of the arrow of time. It is shown that this connection varies a great deal along with these formulations of the second law. According to the famous formulation by Planck, the second law expresses the irreversibility of natural processes. But in many other formulations irreversibility or even time-reversal non-invariance plays no role. I therefore argue for the view that the second law has nothing to do with the arrow of time.

I discuss the nature of the puzzle about the time‐asymmetry of radiation and argue that its most common formulation is flawed. As a result, many proposed solutions fail to solve the real problem. I discuss a recent proposal of Mathias Frisch as an example of the tendency to address the wrong problem. I go on to suggest that the asymmetry of radiation, like the asymmetry of thermodynamics, results from the initial state of the universe.

Thermodynamics is the science that describes much of the time asymmetric behavior found in the world. This entry's first task, consequently, is to show how thermodynamics treats temporally ‘directed’ behavior. It then concentrates on the following two questions. (1) What is the origin of the thermodynamic asymmetry in time? In a world possibly governed by time symmetric laws, how should we understand the time asymmetric laws of thermodynamics? (2) Does the thermodynamic time asymmetry explain the other temporal asymmetries? Does it account, for instance, for the fact that we know more about the past than the future? The discussion thus divides between thermodynamics being an explanandum or explanans. In the former case the answer will be found in philosophy of physics; in the latter case it will be found in metaphysics, epistemology, and other fields, though in each case there will be blurring between the disciplines.

Or better: time asymmetry in thermodynamics. Better still: time asymmetry in thermodynamic phenomena. “Time in thermodynamics” misleadingly suggests that thermodynamics will tell us about the fundamental nature of time. But we don’t think that thermodynamics is a fundamental theory. It is a theory of macroscopic behavior, often called a “phenomenological science.” And to the extent that physics can tell us about the fundamental features of the world, including such things as the nature of time, we generally think that only fundamental physics can. On its own, a science like thermodynamics won’t be able to tell us about time per se. But the theory will have much to say about everyday processes that occur in time; and in particular, the apparent asymmetry of those processes. The pressing question of time in the context of thermodynamics is about the asymmetry of things in time, not the asymmetry of time, to paraphrase Price ( , ). I use the title anyway, to underscore what is, to my mind, the centrality of thermodynamics to any discussion of the nature of time and our experience in it. The two issues—the temporal features of processes in time, and the intrinsic structure of time itself—are related. Indeed, it is in part this relation that makes the question of time asymmetry in thermodynamics so interesting. This, plus the fact that thermodynamics describes a surprisingly wide range of our ordinary experience. We’ll return to this. First, we need to get the question of time asymmetry in thermodynamics out on the table.

This paper investigates what the source of time-asymmetry is in thermodynamics, and comments on the question whether a time-symmetric formulation of the Second Law is possible.