David Bourget (Western Ontario)
David Chalmers (ANU, NYU)
Rafael De Clercq
Jack Alan Reynolds
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British Journal for the Philosophy of Science 61 (3):485-512 (2010)
‘Water is H 2 O’ is naturally construed as an equivalence. What are the things to which the two predicates ‘is water’ and ‘is H 2 O’ apply? The equivalence presupposes that substance properties are distinguished from phase properties. A substance like water (H 2 O) exhibits various phases (solid, liquid, gas) under appropriate conditions, and a given (say liquid) phase may comprise several substances. What general features distinguish substance from phase properties? I tackle these questions on the basis of an interpretation of a theorem of thermodynamics known as Gibbs' phase rule which systematically relates these two kinds of feature of matter. The interpretation develops the idea that the things substance and phase predicates apply to are quantities of matter which sustain mereological relations and operations and exploits these mereological features in distinguishing the two kinds of property. Gibbs' phase rule is a macroscopic principle applicable for macroscopic intervals of time. Bringing intervals of time into the picture calls for a more detailed consideration of the relation between macroscopic equilibria and the corresponding dynamic equilibria at the microlevel and throws into question the simple idea that quantities can always be regarded as collections of molecules. The account provides some insight into how the continuous, macroscopic conception of matter (‘gunk’) is reconciled with the discrete microscopic conception and illuminates the interpretation of substances present in mixtures
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Citations of this work BETA
Michael Weisberg & Paul Needham (2010). Matter, Structure, and Change: Aspects of the Philosophy of Chemistry. Philosophy Compass 5 (10):927-937.
P. Needham (2013). Process and Change: From a Thermodynamic Perspective. British Journal for the Philosophy of Science 64 (2):395-422.
Paul Needham (2012). Natural Kind Thingamajigs. International Studies in the Philosophy of Science 26 (1):97 - 101.
Robin Findlay Hendry (2010). Entropy and Chemical Substance. Philosophy of Science 77 (5):921-932.
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Paul Needham (2004). Continuants and Processes in Macroscopic Chemistry. Axiomathes 14 (1-3):237-265.
Gábor Forrai (2010). Locke on Substance in General. Locke Studies 10:27-59.
S. Marc Cohen (2009). Substances. In Georgios Anagnostopoulos (ed.), A Companion to Aristotle. Blackwell-Wiley.
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