The aim of this article is to analyse the relation between the second law of thermodynamics and the so-called arrow of time. For this purpose, a number of different aspects in this arrow of time are distinguished, in particular those of time-reversal (non-)invariance and of (ir)reversibility. Next I review versions of the second law in the work of Carnot, Clausius, Kelvin, Planck, Gibbs, Caratheodory and Lieb and Yngvason, and investigate their connection with these aspects of the arrow of time. It (...) is shown that this connection varies a great deal along with these formulations of the second law. According to the famous formulation by Planck, the second law expresses the irreversibility of natural processes. But in many other formulations irreversibility or even time-reversal non-invariance plays no role. I therefore argue for the view that the second law has nothing to do with the arrow of time. (shrink)

We introduce a simple model for so-called spin-echo experiments. We show that the model is a mincing system. On the basis of this model we study fine-grained entropy and coarse-grained entropy descriptions of these experiments. The coarse-grained description is shown to be unable to provide an explanation of the echo signals, as a result of the way in which it ignores dynamically generated correlations. This conclusion is extended to the general debate on the foundations of statistical mechanics. We emphasize the (...) need for an appropriate mechanism to explain the gradual suppression over time of the correlations in a thermodynamic system. We argue that such a mechanism can only be provided by the interventionist approach, in which the interaction of the system with its environment is taken into account. Irreversible behavior is then seen to arise not as a result of limited measurement accuracy , but as a result of the fact that thermodynamic systems are limited systems which interact with their environment. A detailed discussion is given of recent objections to the interventionist approach in the literature. (shrink)

Does not the theory of a general tendency of entropy to diminish [sic] take too much for granted? To a certain extent it is supported by experimental evidence. We must accept such evidence as far as it goes and no further. We have no right to supplement it by a large draft of the scientific imagination.

We argue that, contrary to some analyses in the philosophy of science literature, ergodic theory falls short in explaining the success of classical equilibrium statistical mechanics. Our claim is based on the observations that dynamical systems for which statistical mechanics works are most likely not ergodic, and that ergodicity is both too strong and too weak a condition for the required explanation: one needs only ergodic-like behaviour for the finite set of observables that matter, but the behaviour must ensure that (...) the approach to equilibrium for these observables is on the appropriate time-scale. (shrink)

This paper investigates what the source of time-asymmetry is in thermodynamics, and comments on the question whether a time-symmetric formulation of the Second Law is possible.

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Interventionism is an approach to the foundations of statistical mechanics which says that to explain and predict some of the thermodynamic phenomena we need to take into account the inescapable effect of environmental perturbations on the system of interest, in addition to the system's internal dynamics. The literature on interventionism suffers from a curious dual attitude: the approach is often mentioned as a possible framework for understanding statistical mechanics, only to be quickly and decidedly dismissed. The present paper is an (...) attempt to understand this attraction-repulsion story. It offers a version of interventionism that appears to be defensible, and shows that this version can meet the main objections raised against it. It then investigates some of the philosophical ideas underlying interventionism, and proposes that these may be the source of the resentment interventionism encounters. This paves the way to see some features and consequences of interventionism, often taken to be shortcomings, as philosophically advantageous. (shrink)

After reviewing recent literature from physics and philosophy, it is concluded that we are still far from having a satisfying explanation of the nature and origins of irreversibility. It is proposed that the most fruitful approach to this problem is to concentrate on conditions needed for a rigorous derivation of the Boltzmann equation.