History of Chemistry

This book examines the way in which Robert Boyle seeks to accommodate his complex chemical philosophy within the framework of a mechanistic theory of matter. More specifically, the book proposes that Boyle regards chemical qualities as properties that emerged from the mechanistic structure of chymical atoms. Within Boyle’s chemical ontology, chymical atoms are structured concretions of particles that Boyle regards as chemically elementary entities, that is, as chemical wholes that resist experimental analysis. Although this interpretation of Boyle’s chemical philosophy has (...) already been suggested by other Boyle scholars, the present book provides a sustained philosophical argument to demonstrate that, for Boyle, chemical properties are dispositional, relational, emergent, and supervenient properties. This argument is strengthened by a detailed mereological analysis of Boylean chymical atoms that establishes the kind of theory of wholes and parts that is most consistent with an emergentist conception of chemical properties. The emergentist position that is being attributed to Boyle supports his view that chemical reactions resist direct explanation in terms of the mechanistic properties of fundamental particles, as well as his position regarding the scientific autonomy of chymistry from mechanics and physics. (shrink)

One of several important issues that inform contemporary philosophy of chemistry is the issue of structural explanation, precisely because modern chemistry is primarily concerned with microstructure. This paper argues that concern over microstructure, albeit understood differently than it is today, also informs the chemical philosophy of Robert Boyle. According to Boyle, the specific microstructure of ‘chymical atoms’, understood in geometric terms, accounts for the unique essential properties of different chemical substances. Because he considers the microstructure of ‘chymical atoms’ as semi-permanent, (...) Boyle considers these stable entities as operationally irreducible, even if they are not ontologically fundamental. While it is generally believed that our contemporary concern over structural explanation is a function of modern chemistry’s emphasis on microstructure, this discussion of structural explanation in Boyle will serve as a case study to illustrate the manner in which many of our contemporary concerns have deeply historical origins and the manner in which the history of chemistry can substantively inform issues in contemporary philosophy of chemistry. (shrink)

Greatly detailed history of design changes of the eudiometer; unfortunately the annotation on many diagrams is illegible.

Since the early nineteenth century a membrane or wall has been cenptral to the cell’s identity as the elementary unit of life. Yet the literally and metaphorically marginal status of the cell membrane made it the site of clashes over the definition of life and the proper way to study it. In this article I show how the modern cell membrane was conceived of by analogy to the first “artificial cell,” invented in 1864 by the chemist Moritz Traube (1826–1894), and (...) reimagined by the plant physiologist Wilhelm Pfeffer (1845–1920) as a precision osmometer. Pfeffer’s artificial cell osmometer became the conceptual and empirical basis for the law of dilute solutions in physical chemistry, but his use of an artificial analogue to theorize the existence of the plasma membrane as distinct from the cell wall prompted debate over whether biology ought to be more closely unified with the physical sciences, or whether it must remain independent as the science of life. By examining how the histories of plant physiology and physical chemistry intertwined through the artificial cell, I argue that modern biology relocated vitality from protoplasmic living matter to nonliving chemical substances—or, in broader cultural terms, that the disenchantment of life was accompanied by the (re)enchantment of ordinary matter. (shrink)

In his account of scientific revolutions, Thomas Kuhn suggests that after a revolutionary change of theory, it is as if scientists are working in a different world. In this paper, we aim to show that the notion of world change is insightful. We contrast the reporting of the discovery of neon in 1898 with the discovery of hafnium in 1923. The one discovery was made when elements were identified by their atomic weight; the other discovery was made after scientists came (...) to classify elements by their atomic number. By considering two instances of the reporting of the discovery of a new chemical element 25 years apart, we argue that it becomes clear how chemists can be said to have been responding to different worlds as a result of the change in the concept of a chemical element. They saw, did, and reported different things as they conducted their research on the new chemical elements. (shrink)

Roughly, instrumentalism is the view that science is primarily, and should primarily be, an instrument for furthering our practical ends. It has fallen out of favour because historically influential variants of the view, such as logical positivism, suffered from serious defects. -/- In this book, however, Darrell P. Rowbottom develops a new form of instrumentalism, which is more sophisticated and resilient than its predecessors. This position—‘cognitive instrumentalism’—involves three core theses. First, science makes theoretical progress primarily when it furnishes us with (...) more predictive power or understanding concerning observable things. Second, scientific discourse concerning unobservable things should only be taken literally in so far as it involves observable properties or analogies with observable things. Third, scientific claims about unobservable things are probably neither approximately true nor liable to change in such a way as to increase in truthlikeness. -/- There are examples from science throughout the book, and Rowbottom demonstrates at length how cognitive instrumentalism fits with the development of late nineteenth- and early twentieth-century chemistry and physics, and especially atomic theory. Drawing upon this history, Rowbottom also argues that there is a kind of understanding, empirical understanding, which we can achieve without having true, or even approximately true, representations of unobservable things. In closing the book, he sets forth his view on how the distinction between the observable and unobservable may be drawn, and compares cognitive instrumentalism with key contemporary alternatives such as structural realism, constructive empiricism, and semirealism. -/- Overall, this book offers a strong defence of instrumentalism that will be of interest to scholars and students working on the debate about realism in philosophy of science. (shrink)

In this paper I defend, against Eric Scerri’s objections, the following theses: that Lavoisier and Mendeleev shared a ‘core conception’ of chemical element, and that this core conception underwrites referential continuity in the names of particular elements.Keywords: Antoine Lavoisier; Dmitri Mendeleev; Chemical elements; Substance; Natural kinds; Reference.

This article is a translation into english of a lecture given by paneth in 1931. The content of the work is described by the section titles: (1) the need for epistemological clarification of the fundamental concepts of chemistry, (2) the concept of substance in chemistry, (3) the epistemological standpoint of the ancient atomists, (4) the epistemological position of the concept of element introduced by lavoisier, (5) the double meaning of the chemical concept of element: 'basic substance' and 'simple substance', And (...) (6) the double meaning of other chemical concepts. Sections (4)-(6) are published in the following number of this journal. (staff). (shrink)

I will trace the little known prehistory and parts of the better known history of CO 2 by investigating some of the names it has been given from Antiquity to the present day. In Antiquity, the words pneuma or spiritus letalis designated both a supernatural force and an exhalation that emanated from certain caves. We will see how CO 2 gradually came to be regarded as something natural, a gas and then substance.

Today, the lipid bilayer structure is nearly ubiquitous, taken for granted in even the most rudimentary introductions to cell biology. Yet the image of the lipid bilayer, built out of with lipids with heads and tails, went from having obscure origins deep in colloid chemical theory in 1924 to being “obvious to any competent physical chemist” by 1935. This chapter examines how this schematic, strictly heuristic explanation of the idea of molecular orientation was developed within colloid physical chemistry, and how (...) the image was transformed into a reflection of the reality and agency of lipid molecules in the biological microworld. Whereas in physical and colloid chemistry these images considered secondary to instrumental measurement and mathematical modeling of surface phenomena, in biology the manipulable image of the lipid on paper became an essential tool for the molecularization of the cell. (shrink)

Traditionally, the so-called ‘redintegration experiment’ is at the center of the comments on the supposed Boyle/Spinoza correspondence. A. Clericuzio argued (refuting the interpretation by R.A. & M.B. Hall) in his influential publications that, in De nitro, Boyle accounted for the ‘redintegration’ of saltpeter on the grounds of the chemical properties of corpuscles and did not make any attempt to deduce them from the mechanical principles. By contrast, this paper claims that with his De nitro Boyle wanted to illustrate and promote (...) precisely his new Corpuscular or Mechanical Philosophy, and that he did significant attempts to explain the phenomena in terms of mechanical qualities. Boyle had borrowed the ‘redintegration experiment’ from R. Glauber and used it as a tool to prove that his philosophy was the right alternative for the Peripatetic and Paracelsian theory of qualities of bodies. Consequently, Clericuzio’s characterization of the Boyle/Spinoza controversy as a discussion between a strict mechanical philosopher and a chemist is problematic and should be revised. (shrink)

Kant conceives of chemical dissolutions as involving the infinite division and subsequent blending of solvent and solute. In the resulting continuous solution, every subvolume contains a uniform proportion of each reactant. Erich Adickes argues that this account stands in tension with other aspects of Kant’s Critical philosophy and his views on infinity. I argue that although careful analysis of Kant’s conception of dissolution addresses Adickes’ objections, the infinite division inherent to the process is beyond our human cognition, for Kant. Nevertheless, (...) such infinite division may be considered as an idea of reason to make comprehensible chemical reactions, revealing reason to play a pivotal role in the foundations of chemistry. (shrink)

I critically examine Stewart’s suggestion that we should weigh the various predictions Mendeleev made differently. I argue that in his effort to justify discounting the weight of some of Mendeleev’s failures, Stewart invokes a principle that will, in turn, reduce the weight of some of the successful predictions Mendeleev made. So Stewart’s strategy will not necessarily lead to a net gain in Mendeleev’s favor.

I draw attention to one of the most important sources of Kuhn’s ideas in Structure of Scientific Revolutions. Contrary to the popular trend of focusing on external factors in explaining Kuhn’s views, factors related to his social milieu or personal experiences, I focus on the influence of the books and articles he was reading and thinking about in the history of science, specifically, sources in the history of chemistry. I argue that there is good reason to think that the history (...) of chemistry had a profound influence on Kuhn’s thinking, and what is remarkable is that this has eluded our attention for so long. I also argue that his interest in the history of chemistry was due to the influence of James B. Conant and Leonard Nash. (shrink)

When scientists put forward hypotheses, they sometimes involve new kinds of entities, which we can call 'hypothetical entities.' Hypothetical entities are pervasive in the sciences, and some examples include caloric and, up until very recently, the Higgs boson. Some hypothetical entities are discovered, as was the case with the Higgs boson, while scientists conclude that others, like caloric, do not exist. Hypothetical entities pose a number of important challenges for the philosophy of science, and my goal is to develop and (...) defend what I will call the suppositionalist view of hypothetical entities. In chapter 1, I examine the extant views of hypothetical entities, which I draw from the scientific realism debate. I argue that these views are all committed to the claim that terms for hypothetical entities putatively refer to empirical entities. In chapter 2, I develop the suppositionalist view of hypothetical entities. On this view, terms for hypothetical entities refer to what are called 'objects of supposition.' Examples of such objects from other domains include fictional characters like Superman and mathematical objects like the natural numbers. I draw from analogies with fiction and mathematics in order to develop the suppositionalist view in the scientific domain. In chapter 3, I give a history of a hypothetical entity that I will later use as a test case for views of hypothetical entities. In the late-eighteenth century, Antoine Lavoisier hypothesized that muriatic acid is composed of oxygen and a hypothetical entity called the 'muriatic radical.' In the early-nineteenth century, Humphry Davy's work on muriatic acid showed that it is actually composed of hydrogen and chlorine, and so muriatic acid is hydrochloric acid. Finally, in chapter 4, I use the history of the muriatic radical in order to argue against the extant views, and for the suppositionalist view. I argue that the former are committed to giving a history of the muriatic radical that is either whiggish or incomplete. The latter, however, can give us a non-whiggish history that is more complete, and hence it is preferable to the extant views. (shrink)

Kant’s preoccupation with architectonics is a characteristic and noteworthy aspect of his thought. Various features of Kant’s argumentation and philosophical system are founded on the precise definitions of the various subdomains of human knowledge and the derivative borders among them. One science conspicuously absent from Kant’s routine discussions of the organization of knowledge is chemistry. Whereas sciences such as physics, psychology, and anthropology are all explicitly located in the architectonic, chemistry finds no such place. In this paper, I examine neglected (...) passages from Kant’s corpus as well as texts regarding chemistry that Kant himself read in order to unveil his views on the definition of chemistry and its relations with the other sciences. These considerations reveal chemistry to be the science that studies the changes of matter into new kinds. Yet Kant idiosyncratically believes that such a change requires an infinite division of matter, effected by chemical forces. Although this understanding of chemical change dovetails with Kant’s dynamical, continualist theory of matter, it implies that chemistry cannot be reduced to physics. Thus, although chemistry stands alongside empirical physics as an applied natural science in Kant’s architectonic, it remains a distinct, independent science. (shrink)

Published texts, unpublished documents and, to a lesser extent, artefacts are the stuff from which historians of science fashion their interpretations of the past. From these residues we attempt to reconstruct the lost fabric of personalities, activities and institutions that constituted the practice of science, and to comprehend the flow of thought that was its substance. Like the sensory data of the empirical sciences, these raw materials are not pure chunks of reality. They must be interpreted in the light of (...) contemporary discourse and practice of which they were part. Over time, and in the hands of different commentators they acquire new significance, sometimes of mythic proportions; moreover, they are inevitably viewed in the light of present suppositions and fashions, both scientific and historiographical. (shrink)