Standard descriptions of thermodynamically reversible processes attribute contradictory properties to them: they are in equilibrium yet still change their state. Or they are comprised of non-equilibrium states that are so close to equilibrium that the difference does not matter. One cannot have states that both change and no not change at the same time. In place of this internally contradictory characterization, the term “thermodynamically reversible process” is here construed as a label for a set of real processes of change involving (...) only non-equilibrium states. The properties usually attributed to a thermodynamically reversible process are recovered as the limiting properties of this set. No single process, that is, no system undergoing change, equilibrium or otherwise, carries those limiting properties. The paper concludes with an historical survey of characterizations of thermodynamically reversible processes and a critical analysis of their shortcomings. (shrink)

Sadi Carnot’s 1824 Reflections on the Motive Power of Fire created the new science of thermodynamics. It succeeded in its audacious goal of finding a very general theory of the efficiency of heat engines, by introducing and exploiting the strange and unexpected notion of a thermodynamically reversible process. The notion is internally contradictory. It requires the states of these processes to be both in unchanging equilibrium, with a perfect balance of driving forces, while also changing. The work of Sadi’s father, (...) Lazare Carnot, on the efficiency of ordinary machines provided Sadi with a template of a very general theory of the efficiency of ordinary machines; and a characterization of the most efficient processes in them as those that minimize differences of driving forces and can be run in reverse. Lazare’s work could provide these resources because of its choice of a dissipative ontology of inelastic collisions among hard bodies. This historically ill-fated choice meant that Lazare’s machines were analogous to Sadi’s heat engines in their key aspects: they are built from essentially dissipative processes. Lazare’s strategies for controlling dissipation and optimizing his machines were transferrable to the analogous problems Sadi found in heat engines. The unanswerable historical question is whether Sadi would have sought a general theory of heat engines at all or found these general theoretical devices without the template provided in analogy by the prior work of Lazare. (shrink)

The principle of conservation of energy tells us that ‘energy can neither be created nor destroyed but only transformed’. The validity of the principle is without question. The problem is the concept. Contemporary physicists have asserted that we do not know what energy is. We find, however, 19th century physicists, contemporary physicists and historians of science who converge on the point: Mayer and Joule discovered energy. Therefore, we do not know what energy is, but we know these authors discovered it. (...) What did they then discover? What can we learn from this with regard to the energy concept problem? To deal with this issue, I will distinguish between what the authors did experimentally and what they said about the phenomena. This method of analysis makes the difference in relation to historical works on the subject. In a second step, I will consider the introduction of the energy concept, which is from 1850s, and the reification of the energy in 1880s. Finally, I will address the energy conservation principle and the concept of energy conveyed by this principle in contemporary textbooks. As we shall see, the conservation of a magnitude that we call energy nowadays was discovered by Mayer and Joule; an indestructible and transformable entity was not. Adopting the original conservation principle would be enough to avoid the energy concept problem. (shrink)

This paper is the first part of a three-part project ‘How the principle of energy conservation evolved between 1842 and 1870: the view of a participant’. This paper aims at showing how the new ideas of Mayer and Joule were received, what constituted the new theory in the period under study, and how it was supported experimentally. A connection was found between the new theory and thermodynamics which benefited both of them. Some considerations are offered about the desirability of taking (...) a historical approach to teaching energy and its conservation. (shrink)

An account is given of the emergence of the concept of work as a basic component of mechanics. It was largely an achievement of engineer savants in France during the Bourbon Restoration , with Navier, Coriolis and Poncelet playing the major roles. Some aspects of the eighteenth-century prehistory are described, and also concurrent developments in French engineering. The principal problem areas were friction, hydraulics, machine performance and ergonomics, and especially in the last context the developments became involved with social and (...) even philosophical movements in the 1820s. Education played an important role throughout; several of the principal sources are textbooks. (shrink)

I prove that the three basic propositions of Vasiliev's paraconsistent logic have a semantic interpretation by means of the intuitionist logic. The interpèretation is confirmed by amens of the da Costa's model of Vasiliev's paraconsistent logic.

A re-visitation of Joule’s experiment motivates a critical analysis of thermodynamic notions: heat, total energy, first principle, organization of a scientific theory, its relationships with logic and mathematics. A rational re-construction of thermodynamics is suggested according to the model of a problem-based organization, that Sadi Carnot applied to his formulation. The new formulation accomplishes the long time theoretical process started by Joule’s experiment within physicists community's collective mind, i.e. the process of exiting out Baconian science for suggesting a first theory (...) out Newton’s paradigm, and eventually for introducing a pluralism of incompatible physical theories. (shrink)

The ancient, interlinked questions about the role of chance in the living world and the origins of life, gained new relevance with the development of molecular biology in the twentieth century. In 1970, French molecular biologist Jacques Monod, joint winner of the 1965 Nobel Prize in Physiology or Medicine, devoted a popular book on modern biology and its philosophical implications to these questions, which was quickly translated into English as _Chance and Necessity_. Nine years later, Belgian thermodynamicist Ilya Prigogine, 1977 (...) winner of the Nobel Prize in Chemistry, published a popular book on the history and philosophy of natural sciences with Belgian philosopher Isabelle Stengers. Translated into English under the title _Order out of Chaos_ and widely discussed, the whole book can be seen as a response to Monod on these biological and philosophical questions. This study will trace this intellectual controversy between two Nobel Prize winners defending two opposing scientific and philosophical visions of the living world, rooted in two different scientific disciplines. (shrink)

This inaugural handbook documents the distinctive research field that utilizes history and philosophy in investigation of theoretical, curricular and pedagogical issues in the teaching of science and mathematics. It is contributed to by 130 researchers from 30 countries; it provides a logically structured, fully referenced guide to the ways in which science and mathematics education is, informed by the history and philosophy of these disciplines, as well as by the philosophy of education more generally. The first handbook to cover the (...) field, it lays down a much-needed marker of progress to date and provides a platform for informed and coherent future analysis and research of the subject. -/- The publication comes at a time of heightened worldwide concern over the standard of science and mathematics education, attended by fierce debate over how best to reform curricula and enliven student engagement in the subjects There is a growing recognition among educators and policy makers that the learning of science must dovetail with learning about science; this handbook is uniquely positioned as a locus for the discussion. -/- The handbook features sections on pedagogical, theoretical, national, and biographical research, setting the literature of each tradition in its historical context. Each chapter engages in an assessment of the strengths and weakness of the research addressed, and suggests potentially fruitful avenues of future research. A key element of the handbook’s broader analytical framework is its identification and examination of unnoticed philosophical assumptions in science and mathematics research. It reminds readers at a crucial juncture that there has been a long and rich tradition of historical and philosophical engagements with science and mathematics teaching, and that lessons can be learnt from these engagements for the resolution of current theoretical, curricular and pedagogical questions that face teachers and administrators. (shrink)

The main objective of this dissertation is to philosophically assess how the use of informational concepts in the field of classical thermostatistical physics has historically evolved from the late 1940s to the present day. I will first analyze in depth the main notions that form the conceptual basis on which 'informational physics' historically unfolded, encompassing (i) different entropy, probability and information notions, (ii) their multiple interpretative variations, and (iii) the formal, numerical and semantic-interpretative relationships among them. In the following, I (...) will assess the history of informational thermophysics during the second half of the twentieth century. Firstly, I analyse the intellectual factors that gave rise to this current in the late forties (i.e., popularization of Shannon's theory, interest in a naturalized epistemology of science, etc.), then study its consolidation in the Brillouinian and Jaynesian programs, and finally claim how Carnap (1977) and his disciples tried to criticize this tendency within the scientific community. Then, I evaluate how informational physics became a predominant intellectual current in the scientific community in the nineties, made possible by the convergence of Jaynesianism and Brillouinism in proposals such as that of Tribus and McIrvine (1971) or Bekenstein (1973) and the application of algorithmic information theory into the thermophysical domain. As a sign of its radicality at this historical stage, I explore the main proposals to include information as part of our physical reality, such as Wheeler’s (1990), Stonier’s (1990) or Landauer’s (1991), detailing the main philosophical arguments (e.g., Timpson, 2013; Lombardi et al. 2016a) against those inflationary attitudes towards information. Following this historical assessment, I systematically analyze whether the descriptive exploitation of informational concepts has historically contributed to providing us with knowledge of thermophysical reality via (i) explaining thermal processes such as equilibrium approximation, (ii) advantageously predicting thermal phenomena, or (iii) enabling understanding of thermal property such as thermodynamic entropy. I argue that these epistemic shortcomings would make it impossible to draw ontological conclusions in a justified way about the physical nature of information. In conclusion, I will argue that the historical exploitation of informational concepts has not contributed significantly to the epistemic progress of thermophysics. This would lead to characterize informational proposals as 'degenerate science' (à la Lakatos 1978a) regarding classical thermostatistical physics or as theoretically underdeveloped regarding the study of the cognitive dynamics of scientists in this physical domain. (shrink)

Roughly speaking, classical statistical physics is the branch of theoretical physics that aims to account for the thermal behaviour of macroscopic bodies in terms of a classical mechanical model of their microscopic constituents, with the help of probabilistic assumptions. In the last century and a half, a fair number of approaches have been developed to meet this aim. This study of their foundations assesses their coherence and analyzes the motivations for their basic assumptions, and the interpretations of their central concepts. (...) The most outstanding foundational problems are the explanation of time-asymmetry in thermal behaviour, the relative autonomy of thermal phenomena from their microscopic underpinning, and the meaning of probability. A more or less historic survey is given of the work of Maxwell, Boltzmann and Gibbs in statistical physics, and the problems and objections to which their work gave rise. Next, we review some modern approaches to (i) equilibrium statistical mechanics, such as ergodic theory and the theory of the thermodynamic limit; and to (ii) non-equilibrium statistical mechanics as provided by Lanford's work on the Boltzmann equation, the so-called Bogolyubov-Born-Green-Kirkwood-Yvon approach, and stochastic approaches such as `coarse-graining' and the `open systems' approach. In all cases, we focus on the subtle interplay between probabilistic assumptions, dynamical assumptions, initial conditions and other ingredients used in these approaches. (shrink)