The problem is posed of the prescription of the so-called Boltzmann–Grad limit operator ) for the N-body system of smooth hard-spheres which undergo unary, binary as well as multiple elastic instantaneous collisions. It is proved, that, despite the non-commutative property of the operator \, the Boltzmann equation can nevertheless be uniquely determined. In particular, consistent with the claim of Uffink and Valente that there is “no time-asymmetric ingredient” in its derivation, the Boltzmann equation is shown to be time-reversal symmetric. The (...) proof is couched on the “ab initio” axiomatic approach to the classical statistical mechanics recently developed. Implications relevant for the physical interpretation of the Boltzmann H-theorem and the phenomenon of decay to kinetic equilibrium are pointed out. (shrink)

In this survey, we discuss and analyze foundational issues of the problem of time and its asymmetry from a unified standpoint. Our aim is to discuss concisely the current theories and underlying notions, including interdisciplinary aspects, such as the role of time and temporality in quantum and statistical physics, biology, and cosmology. We compare some sophisticated ideas and approaches for the treatment of the problem of time and its asymmetry by thoroughly considering various aspects of the second law of thermodynamics, (...) nonequilibrium entropy, entropy production, and irreversibility. The concept of irreversibility is discussed carefully and reanalyzed in this connection to clarify the concept of entropy production, which is a marked characteristic of irreversibility. The role of boundary conditions in the distinction between past and future is discussed with attention in this context. The paper also includes a synthesis of past and present research and a survey of methodology. It also analyzes some open questions in the field from a critical perspective. (shrink)

Entropy is ubiquitous in physics, and it plays important roles in numerous other disciplines ranging from logic and statistics to biology and economics. However, a closer look reveals a complicated picture: entropy is defined differently in different contexts, and even within the same domain different notions of entropy are at work. Some of these are defined in terms of probabilities, others are not. The aim of this chapter is to arrive at an understanding of some of the most important notions (...) of entropy and to clarify the relations between them, After setting the stage by introducing the thermodynamic entropy, we discuss notions of entropy in information theory, statistical mechanics, dynamical systems theory and fractal geometry. (shrink)

The purpose of this paper is twofold: a) to explore the compatibility of Minkowski’s space-time representation of the Special theory of relativity with a dynamic conception of space-time; b) to locate its roots in invariant features - like entropic relations - of the propagation of signals in space-time. From its very beginning Minkowski’s four-dimensional space-time was associated with a static view of reality, e.g. a block universe. Einstein added his influential voice to this conception when he wrote: ‘From a “happening” (...) in three-dimensional space, physics becomes (…) an “existence” in the four-dimensional “world”.’ (Einstein, Relativity 1920, 122) Yet it is by no means clear that Minkowski himself was a believer in the block universe. In his 1908 Cologne lecture on ‘Space and Time’ he speaks of a four-dimensional physics but concedes that a ‘necessary’ time order can be established at every world point. Although the conception of the block universe has gained much currency, an alternative view has been in circulation since the 1910s according to which the trajectories of particles constitute histories in space-time. (Robb 1914, Cunningham 1915, Carathéodorys 1924, Schlick 1917, Reichenbach 1924). (shrink)