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The Development of the Theory of Electrolytic Dissociation

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Abstract

The theory of electrolytic dissociation proved to be one of the most controversial in the history of chemistry. This paper examines the evidence proffered by Arrhenius, van't Hoff, and Ostwald in favour of the theory and outlines the objections raised by Armstrong, Fitzgerald, and Pickering. The controversy revolved partly around the nature of the emerging new chemistry and has important implications for the study of the nature of science. Some important observations are made in relation to the teaching and learning of chemistry.

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References

  • Abd-El-Khalick, F. & Lederman, N.: 2000, 'The Influence of History of Science Courses on Students' Views of Nature of Science', Journal of Research in Science Teaching 37(10), 1057–1095.

    Google Scholar 

  • American Association for the Advancement of Science: 1993, Benchmarks for Science literacy, Oxford University Press, New York.

    Google Scholar 

  • Armstrong, H.E.: 1896, 'Letters to the Editor', Nature 55(1413), 78.

    Google Scholar 

  • Armstrong, H.E.: 1927, 'Poor Common salt', Nature 120, 478.

    Google Scholar 

  • Armstrong, H.E.: 1928, 'The nature of Solutions', Nature 121(3037), 48–51.

    Google Scholar 

  • Arons, A.: 1983, 'Achieving Wider Scientific Literacy', Daedauls 112(1), 91–122.

    Google Scholar 

  • Arrhenius, S.: 1887, 'Uber die Dissociation der in Wasser gelosten Stoffe', Zeitschrift fur Physicalische Chemie i, 631–648.

    Google Scholar 

  • Arrhenius, S.: 1902, Textbook of Electrochemistry (translated by John McCrae), Longmans, London.

    Google Scholar 

  • Arrhenius, S.: 1904, 'Development of the Theory of Electrolytic Dissociation', in L. Pearce Williams & H.J. Steffens (eds.), 1978, The History of Science in Western Civilization Vol. 3, University Press of America, Lanham, pp. 299–306.

    Google Scholar 

  • Arrhenius, S.: 1912, 'Electrolytic Dissociation', Journal of the American Chemical Society xxxiv, 353–364.

    Google Scholar 

  • Bianchini, J.A. & Colburn, A.: 2000, 'Teaching the Nature of Science through Inquiry to Prospective Elementary Teachers: A Tale of Two Researchers', Journal of Research in Science Teaching 37(2), 177–209.

    Google Scholar 

  • Board of Studies: 2000, HSC Chemistry Syllabus, NSW Board of Studies, Sydney.

    Google Scholar 

  • de Berg, K.C.: 1990, 'The Historical Development of the Pressure-volume Law for Gases', The Australian Science Teachers Journal 36(1), 14–20.

    Google Scholar 

  • de Berg, K.C.: 1997, 'Student Responses to a Pedagogical History of the Pressure-Volume law', in I. Winchester (ed.), 1997, Toward Scientific Literacy-Proceedings of the 4th IHPSST Conference, University of Calgary, pp. 178–187.

  • De Vries, H.: 1888, Zeitschrift fur Physicalische Chemie 2, 414.

    Google Scholar 

  • Driver, R., Newton, P. & Osborne, J.: 2000, 'Establishing the Norms of Scientific Argumentation in Classrooms', Science Education 84, 287–312.

    Google Scholar 

  • Duschl, R.A.: 1988, 'Abandoning the Scientistic Legacy of Science Education', Science Education 72, 51–62.

    Google Scholar 

  • Ebenezer, J.V. & Erickson, G.L.: 1996, 'Chemistry Students' Conceptions of Solubility: A Phenomenography', Science Education 80(2), 181–201.

    Google Scholar 

  • Ebenezer, J.V. & Gaskell, P.J.: 1995, 'Relational Conceptual Change in Solution Chemistry', Science Education 79(1), 1–17.

    Google Scholar 

  • Fitzgerald, G.F.: 1896, 'Helmholtz Memorial Lecture', Journal of the Chemical Society LXIX, 885–912.

    Google Scholar 

  • Gingras, Y.: 2001, 'What Did Mathematics Do to Physics', History of Science xxxix, 383–416.

    Google Scholar 

  • Gratzer, W.(ed.): 1996, A Bedside Nature, Macmillan, London, p. 123.

    Google Scholar 

  • Heilbron, J.L.: 2002, 'History in Science Education, with Cautionary Tales about the Agreement of Measurement and Theory', Science and Education 11, 321–331.

    Google Scholar 

  • Herroun, E.F.: 1896, 'Letters to the Editor', Nature 55(1416), 152.

    Google Scholar 

  • Heyrovska, R.: 1989, 'A Reappraisal of Arrhenius' Theory of Partial Dissociation of Electrolytes', in J.T. Stock & M.V. Orna (eds.), Electrochemistry, Past and Present, American Chemical Society, Washington DC, pp. 75–91.

    Google Scholar 

  • Jahn, ?.: 1891, Wiedemann's Annalen der Physik und Chemie 43, 280.

    Google Scholar 

  • Kuhn, D.: 1993, 'Science as Argument: Implications for Teaching and Learning Scientific Thinking', Science Education 77, 319–337.

    Google Scholar 

  • Larmor, J.: 1897, 'The Theory of Osmotic Pressure', Nature 55(1432), 545–546.

    Google Scholar 

  • Lederman, N.G.: 1999, 'Teachers' Understanding of the Nature of Science and Classroom Practice: Factors That Facilitate or Impede the Relationship', Journal of Research in Science Teaching 36(8), 916–929.

    Google Scholar 

  • Matthews, M.R.: 1997, 'Introductory comments on Philosophy and Constructivism in Science Education', Science & Education 6(1–2), 5–14.

    Google Scholar 

  • McComas, W.F., Almazroa, H. & Clough, M.P.: 1998, 'The Nature of Science in Science Education: An Introduction', Science & Education 7(6), 511–532.

    Google Scholar 

  • Meichtry, Y.J.: 1999, 'The Nature of Science and Scientific Knowledge: Implications for a Preservice Elementary Methods Course', Science & Education 8(3), 273–286.

    Google Scholar 

  • Morris, J.G.: 1974, A Biologist's Physical Chemistry (2nd edn), Edward Arnold, London, pp. 69–75.

    Google Scholar 

  • Niaz, M.: 2000, 'The Oil Drop Experiment: A Rational Reconstruction of the Millikan-Ehrenhaft Controversy and its Implications for Chemistry Textbooks', Journal of Research in Science Teaching 37(5), 480–508.

    Google Scholar 

  • Noyes, A.A. & Falk, K.G.: 1912, 'Properties of Salt Solutions IV', Journal of the American Chemical Society xxxiv, 455–489.

    Google Scholar 

  • Ostwald, W.: 1884a, Journal fur praktische Chemie 29, 385.

    Google Scholar 

  • Ostwald, W.: 1884b, Journal fur praktische Chemie 30, 93.

    Google Scholar 

  • Partington, J.R.: 1964, A History of Chemistry Vol. 4, Macmillan, London, pp. 672–681.

    Google Scholar 

  • Pearce Williams, L. & Steffens, H.J. (eds.): 1978, The History of Science in Western Civilisation Vol. 3, University Press of America, Lanham, pp. 307–313.

    Google Scholar 

  • Pickering, S.: 1897, 'Letters to the Editor', Nature 55(1419), 223.

    Google Scholar 

  • Raoult, F.M.: 1882a, Comptes Rendus 94, 1517.

    Google Scholar 

  • Raoult, F.M.: 1882b, Comptes Rendus 95, 1881.

    Google Scholar 

  • Raoult, F.M.: 1884, Annales de Chimique Physique 2(vi), 66.

    Google Scholar 

  • Tammann, ?.: 1887, Memoires de l'academie des sciences. Peterburg 35(9).

  • Van't Hoff, J.H. & Reicher,: 1888, Zeitschrift fur Physicalische Chemie 2, 781.

    Google Scholar 

  • Whetham, W.C.D.: 1896, 'Letters to the Editor', Nature 55(1416), 151–152.

    Google Scholar 

  • Whetham, W.C.D.: 1897, 'The Theory of Dissociation into Ions', Nature 55(1435), 606–607.

    Google Scholar 

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De Berg, K.C. The Development of the Theory of Electrolytic Dissociation. Science & Education 12, 397–419 (2003). https://doi.org/10.1023/A:1024438216974

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