Abstract
This study discusses the relationship between Green Chemistry and Environmental Sustainability as expressed in textbooks and articles on Green Chemistry authored by their promoters. It was found that although the Brundtland concept of Sustainable Development/Sustainability has been mentioned often by green chemists, a full analysis of that relationship was almost never attempted. In particular, green chemists have paid scarce attention to the importance of The Second Law of thermodynamics on Environmental Sustainability and the consequences of the limitations it imposes on Green Chemistry, which are discussed in this paper.
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References
Ahluwalia, V.R.: Green Chemistry—Environmentally Benign Reactions. CRC Taylor & Francis Group, Boca Raton (2008)
Anastas, P.T., Warner, J.C.: Green Chemistry: Theory and Practice. Oxford University Press, Oxford (1998)
Anastas, P.T., Williamson, T.C. (eds.): Green Chemistry—Frontiers in Benign Chemistry Syntheses. Oxford UP, Oxford (1998)
Anastas, P.T., Williamson, T.C., Hjeresen, D., Breen, J.J.: Promoting Green Chemistry initiatives. Env. Sc. Technol. 33, 116A–119A (1999)
Anastas, P.T., Bartlett, L.B., Kirchhoff, M.M., Williamson, T.C.: The role of catalysis in the design, development, and implementation of Green Chemistry. Cat. Today 55, 11–22 (2000)
Anastas, P.T., Kirchhoff, M.M., Williamson, T.C.: Catalysis as a foundational pillar of Green Chemistry. Appl. Catal. A 221, 3–13 (2001)
Anastas, P.T., Kirchhoff, M.M.: Origins, current status, and future challenges of Green Chemistry. Acc. Chem. Res. 35, 686–694 (2002)
Anastas, P.: Meeting the challenges to sustainability thorough Green Chemistry. Green Chem. 5, G29–G34 (2003)
Anastas, P., Beach, E.S.: Green Chemistry: the emergence of a transformative framework. Green Chem. Lett. Rev. 1, 9–24 (2007)
Arons, J., van der Kooi, H.J.: Towards a metabolic society: a thermodynamic view. Green Chem. 3, G53–G55 (2001)
Basiago, A.D.: Methods of defining “Sustainability”. Sustain. Dev. 3, 109–119 (1995)
Beach, E.S., Cui, Z., Anastas, P.: Green Chemistry: a design framework for sustainability. Energy Environ. Sci. 2, 1038–1049 (2009)
BSD (Board on Sustainable Development, US National Academy of Sciences): Our Common Journey. National Academy Press, Washington (1999)
Centi, G., Perathoner, S.: Catalysis and sustainable (green) chemistry. Catal. Today 77, 287–297 (2003)
Clark, J.H.: Green Chemistry: challenges and opportunities. Green Chem. 1, 1–8 (1999)
Clark, J.H.: Green Chemistry: today (and tomorrow). Green Chem. 8, 17–21 (2006)
Collins, T.J.: Green Chemistry. MacMillan Encyclopedia of Chemistry, vol. 2, pp. 691–697. Macmillan Publishing, New York (1997)
Daly, H.E.: Steady-State Economics, 2nd edn. Island Press, Washington (1991)
Daly, H.E.: The economic thought of frederick soddy. Hist. Political Econ. 12, 469–488 (1980)
Dichiarante, V., Ravelli, D., Albini, A.: Green Chemistry: state of the art through an analysis of the literature. Green Chem. Lett. Rev. 3, 105–113 (2010)
Ehrenfeld, D.: Sustainability: living with the imperfections. Conserv. Biol. 19, 33–35 (2005)
Georgescu-Roegen, N.: The Entropy Law and the Economic Process. Harvard University Press, Cambridge, Mass (1971)
Goldsmith, E., Allen, R., Allaby, M., John Davoll, J., Lawrence, S. (eds): A blueprint for survival. Penguin Books Ltd, Harmondsworth (1972)
Goodland, R.: The concept of Environmental Sustainability. Annu. Rev. Ecol. Syst. 26, 1–24 (1995)
Graedel, T.E.: Green Chemistry and sustainable development. In: Clark, J.H., Macquarrie, D. (eds.) Handbook of Green Chemistry and Technology, Chapt. 4, pp. 56–61. Wiley, Chichester (2002)
Graedel, T.E.: Green Chemistry as systems science. Pure Appl. Chem. 73, 1243–1246 (2001)
Hjeresen, D.L., Anastas, P., Ware, S., Kirchhof, M.: Green Chemistry progress & challenges. Env. Sci. Technol. 35, 114A–119A (2001)
Hull, Z.: Sustainable Development: premises, understanding and prospects. Sustain. Dev. 16, 73–80 (2008)
Huesemann, M.H.: The limits of technological solutions to sustainable development. Clean Techn. Environ. Policy 5, 8–20 (2003)
Huesemann, M.H.: The failure of eco-efficiency to guarantee sustainability: future challenges for industrial ecology. Environ. Prog. 23, 264–270 (2004)
Jacoby, M.: Securing the supply or rare earths. Chem. Eng. News 88(35), 9–12 (2010)
Jischa, M.F.: Sustainable Development and technology assessment. Chem. Eng. Technol. 21, 628–636 (1998)
Kates, R.W., Parris, T.M., Leiserowitz, A.A.: What is sustainable development? Goals, indicators, values and practice. Environment 47(3), 8–21 (2005)
Khan, M.A.: Sustainable Development: the key concepts, issues and implications. Sustain. Dev. 3, 63–69 (1995)
Kidwai, M., Mohan, R.: Green Chemistry: an innovative technology. Found. Chem. 7, 269–287 (2005)
Kirchhoff, M.M.: Promoting sustainability through Green Chemistry. Resour. Conserv. Recycl. 44, 237–243 (2005)
Lancaster, M.: Green Chemistry—An Introductory Text. Royal Society of Chemistry, Cambridge (2002)
Lancaster, M.: Green Chemistry—An Introductory Text, 2nd edn. Royal Society of Chemistry, Cambridge (2010)
Lélé, S.M.: Sustainable Development: a critical review. World Dev. 19, 607–621 (1991)
Linthrost, J.A.: An overview: origins and development of Green Chemistry. Found. Chem. 12, 55–68 (2010)
Logar, N.: Chemistry, Green Chemistry, and the instrumental valuation of sustainability. Minerva 49, 113–136 (2011)
Machado, A.A.S.C.: Da génese ao ensino da Química Verde. Quim. Nova 34, 535–543 (2011)
Machado, A.A.S.C.: Green Chemistry Education: Towards a Systems Thinking Approach, Plenary Presented at the 4th International IUPAC Conference on Green Chemistry. Foz do Iguaçu, Brasil (2012)
Manley, J.B., Anastas, P., Cue Jr, B.W.: Frontiers in Green Chemistry: meeting the grand challengers for sustainability in R&D and manufacturing. J. Clean. Prod. 16, 743–750 (2008)
Matlack, A.S.: Introduction to Green Chemistry. Marcel Dekker, New York (2001)
Matlack, A.S.: Introduction to Green Chemistry, 2nd edn. CRC Press, Boca Raton (2010)
Matus, K.J.M., Clark, W.C., Anastas, P.T., Zimmerman, J.B.: Barriers to the implementation of Green Chemistry in the United States. Env. Sci. Technol. 46, 10892–10899 (2012)
Nemerow, N.L.: Zero Pollution for Industry—Waste Minimization Through Industrial Complexes. Wiley-Interscince, New York (1995)
Newton, J.L., Freyfogle, E.T.: Sustainability: a dissent. Conserv. Biol. 19, 23–32 (2005)
Nitta, Y., Yoda, S.: Challenging the human crisis: “The trilemma”. Technol. Forecast. Soc. Chang. 49, 175–194 (1995)
Norton, B.G.: Evaluating ecosystems states: two competing paradigms. Ecol. Econ. 14, 113–127 (1995)
Paehke, R.: Environmental politics, sustainability and social science. Environ. Polit 10(4), 1–22 (2001)
Paehke, R.: Sustainability as a bridging concept. Conserv. Biol. 19, 36–38 (2005)
Pawlowski, A.: How many dimensions does sustainable development have? Sustain. Dev. 16, 81–90 (2008)
Sciubba, E., Zullo, F.: Exergy-based population dynamics. J. Ind. Ecol. 15, 172–184 (2011)
Soddy, F.: Cartesian Economics: The Bearing of Physical Science upon State Stewardship, Hendersons, London (1922). Available from: http://habitat.aq.upm.es/boletin/n37/afsod.en.html. Accessed 06 November 2012
Soddy, F.: Wealth, Virtual Wealth, and Debt. Allen and Unwin, London (1926)
Soddy, F.: The Role of Money: What it Should be, Contrasted with What it has Become. Routledge, London (1934); fac-simile reprint (2003). Available from: http://archive.org/details/roleofmoney032861mbp. Accessed 06 November 2012
Srivastava, M.M., Sanghi, R. (eds.): Chemistry for Green Environment. Narosa Publishing House, New Delhi (2005)
Thornton, J.: Implementing Green Chemistry: an environmental policy for sustainability. Pure Appl. Chem. 73, 1231–1236 (2001)
Thornton, J.: Beyond risk: an ecological paradigm to prevent global chemical pollution. Int. J. Occup. Environ. Health 6, 318–330 (2000)
Tiezzi, E.: Tempos Históricos, Tempos Biológicos, a Terra ou a Morte: os Problemas da Nova Ecologia. São Paulo, Nobel (1988)
Werner, J.C., Cannon, A.S., Dye, K.K.: Green Chemistry. Environ. Impact Assess. Rev. 24, 775–799 (2004)
Winterton, N.: Sense and sustainability: the role of chemistry, green or otherwise. Clean Techn. Environ. Policy 5, 8–20 (2003)
Winterton, N.: Chemistry for Sustainable Technologies: A Foundation. RCS Publishing, Cambridge, UK (2011), Chapter 6
Woodhouse, E.J., Breyman, S.: Green Chemistry as a social movement. Sci. Techonol. Human Values 30, 199–222 (2005)
WCED (World Commission on Environmental and Development): Our Common Future. Oxford University Press, Oxford (1987)
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To CNPq (Conselho Nacional de Desenvolvimento Científico e Tecnológico, Brasil), as well as CAPES (Coordenação de Aperfeiçoamento de Pessoal de Nível Superior, Brasil) and FCT (Fundação de Ciência e Tecnologia, Portugal), for the award of a collaboration project on “Chemical Education under the Perspective of Green Chemistry and Environmental Sustainability”, project nr 289/11 (Brasil) and 151/11 (Portugal).
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Marques, C.A., Machado, A.A.S.C. Environmental Sustainability: implications and limitations to Green Chemistry. Found Chem 16, 125–147 (2014). https://doi.org/10.1007/s10698-013-9189-x
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DOI: https://doi.org/10.1007/s10698-013-9189-x