A novel cationic heteropolyoxovanadium cluster functionalized with organic ligands: Synthesis and characterization of the fully reduced species [MnIIVIV6O6{2N}6]Cl 2 [Book Review]

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Abstract

The solvothermal reaction of 3N with [4N]3[H3V 10O28] and MnCl2·4H2O in CH3CN and CH3OH yields a novel cationic heteropolyoxovanadium cluster, [MnIIVIV6O6{2N}6] 2+, containing a fully reduced new cyclic {MnV6N6O18} core with the Anderson structure.

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Muhammad Khan
University of Leicester

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