Abstract

A new probabilistic-informational concept, earlier constructed by Mugur-Schächter, is further developed. Associated with Jaynes's principle, this concept permits one to define a measure for the distance between the state of a system evolving under stable constraints and the equilibrium with these constraints. An illustration is given for a gas evolving in a thermostated box. It appears that the free energy of the gas estimates the distance to equilibrium, the estimation being defined in abstract informational-probabilistic terms