This is the first of a pair of papers. It focuses on the development of the most notable phlogistic theories during the period 1766–1791, including the main experiments that their proponents proposed them to interpret. There was a rapid proliferation of late phlogistic theories, particularly from 1784, and the accounts of composition and important implications of the main theories are set out and their issues analysed. Each of them either reached impasses due to internal problems, or included features that made (...) them unacceptable even to other phlogistians. The expositions and analyses of these theories are given in terms of details that were in the literature at the time or otherwise potentially understandable by the participants given contemporary practice. Some relevant methodological aspects of the history of science are discussed, and the secondary literature is briefly surveyed. The second paper deals with the contemporary development of the new chemistry, and with theory comparison and theory choice in the same period. (shrink)

This is the second of a pair of papers, of which the first showed how each of the main late phlogistic theories effectively reached impasses due to internal problems or included features which made them unacceptable even to other phlogistians. This paper deals with theory comparison and theory change. It gives an unprecedentedly detailed comparison between the available theories in 1790–1791, and shows that this was overwhelmingly in favour of the new chemistry. This time period correlates well with many chemists (...) changing to the new theory. There was a plurality of views held by individuals and there was freedom of individual choice concerning theories, yet there was also a widespread and rational change to the new chemistry. (shrink)

ArgumentDuring the two decades before the turning point in Copernicus's personal and scientific development in 1510, he had experience of political activity which has been largely ignored by the existing Copernicus literature but part of which is reconstructed in outline in this paper. Given the close linkage between politics and astrology, Copernicus's likely reaction to astrology is re-examined here. This reconstruction also suggests that the turning point in 1510, when Copernicus left his post as secretary to his uncle Lucas Watzenrode (...) the prince-bishop of Warmia, was not only linked to Copernicus's first version of his heliocentric theory in theCommentariolus, but also to major political setbacks being experienced by Watzenrode during these years, and with the publication of Copernicus's translation of theLettersof Theophylactus Simocatta. Some of these considerations contribute to maintaining the view that Copernicus and his work were in several respects exceptional. (shrink)

During most of Copernicus's life he was an inhabitant of political settings rather than scientific settings. His settings from 1492 to 1500 offered him a large amount of information about astrology. Most of Copernicus's known significant contacts at the Jagiellonian University had expertise in astrology, in some cases at national level. Information was available to Copernicus about the inaccuracies and the difficulties of astrological practice as well as about a notably successful astrologer-patron relationship. The experience of astrological practice that was (...) available to Copernicus in Bologna ranged from the benign to the potentially dangerous, and his departure from Bologna was contemporary with the threat of military reprisals against the town which appeared to show the incorrect outcome of the relevant prediction in Domenico Maria di Novara's prognostication for 1500. After this date Copernicus no longer participated in roles in which prognostication was a duty, he generally inhabited locations that were less potentially dangerous than Bologna was in 1500, and while at some later points he was keen to interest astrologers in his astronomical work, astrology is completely absent from his own explanations of the reasons for his astronomical work. (shrink)

How do we refer to chemical substances, and in particular to chemical elements? This question relates to many philosophical questions, including whether or not theories are incommensurable, the extent to which past theories are later discarded, and issues about scientific realism. This chapter considers the first explicit reference to types of colorless air in late-eighteenth-century chemical practice. Reference to a gas by one chemist was generally intended to give others epistemological, methodological, and practical access to the gas. This chapter proposes (...) a causal-descriptive theory of reference for chemical substances. Implications for debates about incommensurability and realism are also briefly noted. (shrink)

ArgumentThe main thesis of this paper is that Copernicus's avoidance of all admission that scripture was contravened inDe revolutionibusand his composition of its new Preface in 1542, as well as the non-publication of Rheticus'sTreatise on Holy Scripture and the Motion of the Earth, were influenced by the early information they received on the failure of the 1541 Regensburg Protestant-Catholic colloquy, among the major consequences of which were significant increases in the problems concerning publishing works which contravened scripture. This is supported (...) by examining Rheticus's first letter to Paul Eber in conjunction with the documents on the Regensburg colloquy and on censorship in Nuremberg, as well as with the existing literature on Copernicus and his context. In view of the main thesis, Copernicus's apparent dedication of the work to the Pope merits additional explanation, and the second thesis is that components of explanations for several aspects of those parts of the Preface that relate to the Papacy and to theologians can be provided via comparisons with previous diplomacy between Warmia and the Papacy which occurred or was being referred to during Copernicus's time. This is supported by examining these parts of the Preface in the light of a selection of the relevant documents. (shrink)

In some views in the history, philosophy and social studies of chemistry, Joseph Priestley is at least as well-known and cited for his objections to the new chemistry and his promotion of his own late version of the theory of phlogiston, as for his early series of discoveries about types of air for which he had become famous. These citations are generally not associated with any detailed indications about his late work from 1788 onwards and his late phlogistic theory, of (...) which there has not been a detailed study. This paper undertakes a detailed study of Priestley’s late work on water and related airs. He put forward a theory to support which his apparatus and initial substances would have needed to exclude impurities altogether. His theory did not take into account the solutions to the difficulties with the experiment which had been comprehensively understood and published by the phlogistian Cavendish several years previously, and with which the Lavoisians were in agreement. Priestley readily and fundamentally changed his interpretations of experiments in order to support the theory he currently favoured, and he was highly selective about replying about the criticisms of any opponent. This detailed analysis shows many divergences between his own practices and aspects of his objections to the new chemistry, which have implications for those stances in the secondary literature which do not question his objections. Accordingly, this study has implications concerning the nature of chemistry and other sciences, how they do progress and how they should progress. (shrink)

A recent paper by Hoyningen-Huene argues that the Chemical Revolution is an excellent example of the success of Kuhn’s theory. This paper gives a succinct account of some counter-arguments and briefly refers to some further existing counter-arguments. While Kuhn’s theory does have a small number of more or less successful elements, it has been widely recognised that in general Kuhn’s theory is a “preformed and relatively inflexible framework” (1962, p. 24) which does not fit particular historical examples well; this paper (...) clarifies that those examples include the Chemical Revolution. (shrink)