Abstract
A new axiomatic characterization with a minimum of conditions for entropy as a function on the set of states in quantum mechanics is presented. Traditionally unspoken assumptions are unveiled and replaced by proven consequences of the axioms. First the Boltzmann–Planck formula is derived. Building on this formula, using the Law of Large Numbers—a basic theorem of probability theory—the von Neumann formula is deduced. Axioms used in older theories on the foundations are now derived facts.
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Åberg, J.: Truly work-like work extraction via a single-shot analysis. Nat. Commun. 4, 1925 (2013)
Aczél, J., Forte, B., Ng, C.T.: Why the Shannon and Hartley entropies are ‘Natural’. Adv. Appl. Probab. 6, 131–146 (1974)
Anders, J., Shabbir, S., Hilt, S., Lutz, E.: Landauer’s principle in the quantum domain. Electron. Proc. Theor. Comput. Sci. 26, 13–18 (2010)
Bhatia, R.: Matrix Analysis. Springer, New York (1997)
Boltzmann, L.: Analytischer Beweis des zweiten Hauptsatzes der mechanischen Wärmetheorie aus den Sätzen über das Gleichgewicht der lebendigen Kraft. Sitzb. der Wiener Akad. LXIII, 712–732 (1871)
Boltzmann, L.: Weitere Studien über das Wärmegleichgewicht unter Gasmolekülen. Sitzb. der Wiener Akad. LXVI, 275–370 (1872)
Boltzmann, L.: Über die Beziehung zwischen dem zweiten Hauptsatze der mechanischen Wärmetheorie und der Wahrscheinlichkeitsrechnung respektive den Sätzen über das Wärmegleichgewicht. Sitzb. der Wiener Akad. LXXVI, 373–435 (1877)
Bratteli, O., Robinson, D.W.: Operator Algebras and Quantum Statistical Mechanics II. Springer, New York (1981)
Brönnimann, D.: Die Entwicklung des Wahrscheinlichkeitsbegriffs von 1654 bis 1718. ftp://stat.ethz.ch/Masters.../Daniel Broennimann-Wahrschkeit
Cohen, E.G.D., Thirring, W.: The Boltzmann Equation. Springer, Wien (1973)
Cohen-Tannoudji, C., Guéry-Odelin, D.: Advances in Atomic Physics. World Scientific, Singapore (2011)
Cover, T.M., Thomas, J.A.: Elements of Information Theory. Wiley Interscience, Hoboken (2006)
Dahlsten, O.C.O., Renner, R., Rieper, E., Vedral, V.: Inadequacy of von Neumann entropy for characterizing extractable work. New J. Phys. 13(5), 053015 (2011), arXiv:0908.0424
Dupuis, F., et al.: Generalized entropies. In: Proceedings of the XVIIth International Conference on Mathematics and Physics, Aalborg, Denmark (2012). arXiv:1211.3141
Egloff, D., et al.: Laws of thermodynamics beyond the von Neumann regime. arXiv:1207.0434
Einstein, A.: Beiträge zur Quantentheorie. Verh. Deutsch. Phys. Ges. 12, 820–828 (1914)
Gallavotti, G., Reiter, W.L., Yngvason, J. (eds.).: Boltzmann’s Legacy. European Mathematical Society Publ. House (2008)
Gibbs, J.W.: Elementary Principles in Statistical Mechanics. Yale University Press (1902), republicated by Dover Publ., Inc. N.Y. (1960)
Ingarden, R.S., Kossakowski, A., Ohya, M.: Information Dynamics and Open Systems. Kluwer Academic Publishers (1997)
Klein, M.J.: The Development of Boltzmann’s Statistical Ideas. In: Cohen, E.G.D., Thirring, W. (eds.) The Boltzmann Equation. Springer, Wien (1973)
Lieb, E.H., Yngvason, J.: A guide to entropy and the second law of thermodynamics. Not. Am. Math. Soc. 45, 571–581 (1999), Erratum 314, 699 (1999)
Lieb, E.H., Yngvason, J.: The physics and mathematics of the second law of thermodynamics. Phys. Rep. 310, 1–96 (1999), Erratum 314, 699 (1999)
Lieb, E.H., Yngvason, J.: A fresh look at entropy and the second law of thermodynamics. Phys. Today 310, 32–37 (2000)
Lieb, E.H., Yngvason, J.: The Mathematical Structure of the Second Law of Thermodynamics. arXiv:math-ph/0204007
Nagaoka, H., Hayashi, M.: An information-spectrum approach to classical and quantum hypothesis testing for simple hypotheses. IEEE Trans. Inf. Theory 53(2), 534–549 (2007)
Nielsen, M.A., Chuang, I.L.: Quantum Computation and Quantum Information. Cambridge Inversity Press, Cambridge, UK (2000)
Ochs, W.: A new axiomatic characterization of the von Neumann entropy. Rep. Math. Phys. 3, 109–120 (1975)
Planck, M.: Über das Gesetz der Energieverteilung im Normalspektrum. Ann. Phys. 4(4), 553–563 (1901)
Planck, M.: Vorlesungen über die Theorie der Wärmestrahlung. Barth, Leipzig (1906)
Renner, R.: Security of quantum key distribution. Dissertation. arXiv:0512258v2
Ruskai, M.B.: Inequalities for quantum entropy: a review with conditions for equality. J. Math. Phys. 43, 4358–4375 (2002)
Schrödinger, E.: Statistical Thermodynamics. Cambridge University Press, London (1946)
Shannon, C.F.: A mathematical theory of communication. Bell Syst. Tech. J. 27, 379–423, 623–656, July, October (1948)
Shannon, C.F., Weaver, W.: The Mathematical Theory of Communication. University of Illinois Press, Chicago (1949)
Szilard, L.: Über die Ausdehnung der phänomenologischen Thermodynamik auf die Schwankungserscheinungen. Zeitschrift für Physik. XXXII(10), 753–788 (1925)
Tomamichel, M.: A Framework for Non-Asymptotic Quantum Information Theory. Dissertation, arXiv:1203.2142
Tomamichel, M., Colbeck, R., Renner, R.: A fully quantum asymptotic equipartition property. IEEE Trans. Inf. Theory 55(12), 5840–5847 (2009)
Uhlmann, A.: Sätze über Dichtematrizen. Wiss. Z. Karl-Marx-Univ. 20, 633–637 (1971)
Uhlmann, A.: Wiss. Z. Karl-Marx-Univ. Endlich-dimensionale Dichtematrizen I 21, 421–452 (1972)
Uhlmann, A.: Wiss. Z. Karl-Marx-Univ. Endlich-dimensionale Dichtematrizen II 22, 139–177 (1973)
von Neumann, J.: Gött. Nachr. Thermodynamik quantenmechanischer Gesamtheiten 1, 273–291 (1929)
von Neumann, J.: Mathematische Grundlagen der Quantenmechanik. Springer, Berlin (1932)
Wehrl, A.: How chaotic is a state of a quantum system? Rep. Math. Phys. 6, 15–28 (1974)
Wehrl, A.: General properties of entropy. Rev. Mod. Phys. 50, 221–260 (1978)
Wehrl, A.: Information-Theoretical Aspects of Quantum-Mechanical Entropy. Univ. Vienna preprint UWThPh-1990-20, unpublished (1990)
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The author thanks the referees for important hints, and he gives many thanks to Elliott Lieb and Jakob Yngvason for discussions.
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Baumgartner, B. Characterizing Entropy in Statistical Physics and in Quantum Information Theory. Found Phys 44, 1107–1123 (2014). https://doi.org/10.1007/s10701-014-9832-y
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DOI: https://doi.org/10.1007/s10701-014-9832-y