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Argon and the Periodic System: the Piece that Would not Fit

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Abstract

The discovery of the noble gases and their incorporation into the periodic system are examined in this paper. A chronology of experimental reports on argon and helium and the properties relevant to their nature and position in the periodic system is presented. Proposals on the nature of argon and helium that appeared in the aftermath of their discovery are examined in light of the various empirical and theoretical considerations that supported and contradicted them. ``The piece that would not fit'' refers not only to argon, the element that at first seemed not to fit into the periodic system, but also to the piece or pieces of evidence that various researchers and observers were prepared to discard or discount in coming to terms with the newly discovered gases.

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REFERENCES

  • W.W. Andrews. The Position of Argon in the Periodic System. Chemical News 71: 235, 1895.

    Google Scholar 

  • BAAS (British Association for the Advancement of Science). Report of the 64th Meeting of the British Association for the Advancement of Science, p. 614, 1894.

  • C.E. Basevi. Argon and the Kinetic Theory. Nature 52: 221-222, 1895.

    Google Scholar 

  • Marcellin Berthelot. Essais pour faire entrer l'argon en combinaison chimique. Comptes Rendus 120: 581-585, 1895a.

    Google Scholar 

  • Marcellin Berthelot. Nouvelles recherches de M. Ramsay sur l'argon et sur l'hélium. Comptes Rendus 120: 660-662, 1895b (translated as New Researches by Prof. Ramsay on Argon and Helium. Chemical News 71: 176, 1895).

    Google Scholar 

  • Marcellin Berthelot. Sur l'argon et l'hélium. Comptes Rendus 120: 1049, 1895c (excerpt translated as On Argon and Helium. Chemical News 71: 259, 1895).

    Google Scholar 

  • Bohuslav Brauner. Ueber das Atomgewicht des Tellurs. Berichte 16: 3055-3056, 1883.

    Google Scholar 

  • Bohuslav Brauner. Some Remarks on 'Argon'. Chemical News 71: 79, 1895a.

    Google Scholar 

  • Bohuslav Brauner. Note on Gases of the Hclium and Argon Type. Chemical News 71: 271, 1895b.

    Google Scholar 

  • Bohuslav Brauner. Argon, Helium, and Prout's Hypothesis. Chemical News 74: 223-224. 1896.

    Google Scholar 

  • Chemical News. A Supposed New Gaseous Element in the Atmosphere. Chemical News 70: 87, 1894a.

    Google Scholar 

  • Chemical News. The Royal Society Anniversary Meeting, November 30th, 1894. Chemical News 70: 288-292, 303-306, 1894b.

    Google Scholar 

  • Chemical News. Chemical Society, Ordinary Meeting, December 6th, 1894. Chemical News 70: 300-303, 1894c.

    Google Scholar 

  • Chemical News. The Royal Society, Thursday, January 31st 1895. Chemical News 71: 51-63, 1895.

    Google Scholar 

  • Chemical Society. Annual General Meeting. Journal of the Chemical Society (Transactions) 67: 1105-1172, 1895.

    Article  Google Scholar 

  • Per Cleve. Sur la densité de l'hélium. Comptes Rendus 120: 1212, 1895 (translated as On the Density of Helium. Chemical News 71: 283, 1895).

    Google Scholar 

  • William Crookes. On the Spectra of Argon. Philosophical Transactions of the Royal Society 186A: 243-251, 1895.

    Google Scholar 

  • William Crookes. On the Position of Helium, Argon, and Krypton in the Scheme of Elements. Proceedings of the Royal Society 63: 408-411, 1898.

    Google Scholar 

  • R.M. Deeley. Helium and Argon: their Places Among the Elements. Chemical News 72: 297-298, 1895.

    Google Scholar 

  • James Dewar. The New Element. Chemical News 70: 87, 1894a.

    Google Scholar 

  • James Dewar. The New Element. Chemical News 70: 87-88, 1894b (the second of two letters with the same title).

    Google Scholar 

  • James Dewar. A Supposed New Gaseous Element in the Atmosphere. Chemical News 70: 109, 1894c.

    Google Scholar 

  • James Dewar. The Relative Behaviour of Chemically Prepared and of Atmospheric Nitrogen in the Liquid State. Proceedings of the Chemical Society 10: 222-225, 1894d.

    Google Scholar 

  • Carmen J. Giunta. Using Case Histories to Teach Scientific Method: the Case of Argon. Journal of Chemical Education 75: 1322-1325, 1998.

    Google Scholar 

  • John Hall Gladstone. Argon. Nature 51: 389-390, 1895.

    Google Scholar 

  • Erwin N. Hiebert. Historical Remarks on the Discovery of Argon, the First Noble Gas, in Herbert H. Hyman (Ed.), Noble-Gas Compounds. University of Chicago, Chicago, pp. 3-20, 1963.

    Google Scholar 

  • Richard F. Hirsh. A Conflict of Principles: The Discovery of Argon and the Debate Over its Existence. Ambix 28: 121-130, 1981.

    Google Scholar 

  • Keith J. Laidler. The World of Physical Chemistry. Oxford University Press, Oxford, 1993.

    Google Scholar 

  • Paul-Émile Lecoq de Boisbaudran. Remarques sur les poids atomiques. Comptes Rendus 120: 361-362, 1895a.

    Google Scholar 

  • Paul-Émile Lecoq de Boisbaudran. Classification des éléments chimiques. Comptes Rendus 120: 1097-1103, 1895b (translated as Classification of the Chemical Elements. Chemical News 71: 271-273, 1895).

    Google Scholar 

  • J. Norman Lockyer. On the New Gas Obtained from Uraninite, Second Note. Proceedings of the Royal Society 58: 113-116, 1895.

    Google Scholar 

  • James Clerk Maxwell. Illustrations of the Dynamical Theory of Gases. Philosophical Magazine 19: 19-32; 21-37, 1860.

    Google Scholar 

  • Raphael Meldola. The State of Chemical Science in 1851. Report of the 65th Meeting of the British Association for the Advancement of Science: 639-655, 1895. (Also in Nature 52: 477-484, 1895 and Chemical News 72: 141-148, 151-152, 1895.)

  • Dmitrii Mendeleev. Zeitschrift für Chemie 12: 405-406, 1869 (abstracted from Zhurnal Russkoe Fiziko-Khimicheskoe Obshchestvo 1: 60-77, 1869).

    Google Scholar 

  • Dmitrii Mendeleev. Die periodische Gesetzmassigkeit der chemischen Elemente. Annalen der Chemie und Pharmacie (Suppl. 8): 133-229, 1872.

    Google Scholar 

  • Dmitrii Mendeleev. Professor Mendeléeff on argon. Nature 51: 543, 1895a.

    Google Scholar 

  • Dmitrii Mendeleev. On Argon. Chemical News 72: 14, 1895b.

    Google Scholar 

  • Dmitrii Mendeleev. The Principles of Chemistry (translated from 6th Russian edition by George Kamensky). Longmans, Green, London, 1897.

    Google Scholar 

  • Dmitrii Mendeleev. The Principles of Chemistry (translated from 7th Russian edition by George Kamensky). Longmans, Green, London, 1905.

    Google Scholar 

  • Nature. Chemistry at the British Association. Nature 50: 409-411, 1894a.

    Google Scholar 

  • J.A.R. Newlands. Relations between Equivalents. Chemical News 10: 59, 1864.

    Google Scholar 

  • J.A.R. Newlands. On the 'Law of Octaves'. Chemical News 13: 130, 1866.

    Google Scholar 

  • Nobel Foundation. Chemistry, 1901-1921. Elsevier, Amsterdam, 1966.

    Google Scholar 

  • Karol Olszewski. The Liquefaction and Solidification of Argon. Philosophical Transactions of the Royal Society 186A: 253-257, 1895.

    Google Scholar 

  • W. Preyer. Argon and Helium in the System of the Elements. Chemical News 73: 235-236, 1895.

    Google Scholar 

  • William Ramsay. On a Gas Showing the Spectrum of Helium, the Reputed Cause of D3, One of the Lines in the Coronal Spectrum, Preliminary Note. Proceedings of the Royal Society 58: 65-67, 1895a.

    Google Scholar 

  • William Ramsay. Helium, a Gaseous Constituent of Certain Minerals, Part I. Proceedings of the Royal Society 58: 81-89, 1895b.

    Google Scholar 

  • William Ramsay. Attempt to Liquefy Helium. Nature 52: 544, 1895c.

    Google Scholar 

  • William Ramsay. The Gases of the Atmosphere, Macmillan and Co., London, 1896.

    Google Scholar 

  • William Ramsay. An Undiscovered Gas. Report of the 67th Meeting of the British Association for the Advancement of Science: 593-601, 1897. (Also printed in Nature 56: 378-382, 1897 and Chemical News 76: 91-93, 97-99, 1897.)

  • William Ramsay. J. Norman Collie and Morris Travers, Helium, a Constituent of Certain Minerals. Journal of the Chemical Society (Transactions) 67: 684-701, 1895.

    Article  Google Scholar 

  • William Ramsay and Robert Whytlaw Gray. La densité de l'èmanation du radium. Comptes Rendus 151: 126-128, 1910.

    Google Scholar 

  • William Ramsay and Morris W. Travers. On a New Constituent of Atmospheric Air. Proceedings of the Royal Society 63: 405-408, 1898a.

    Google Scholar 

  • William Ramsay and Morris W. Travers. On the Companions of Argon. Proceedings of the Royal Society 63: 437-440, 1898b.

    Google Scholar 

  • William Ramsay and Morris W. Travers. On the Extraction from Air of the Companions of Argon. Report of the 68th Meeting of the British Association for the Advancement of Science: 828-830, 1898c.

  • F. Rang. The Period-Table. Chemical News 72: 200-201, 1895.

    Google Scholar 

  • Lord Rayleigh. Argon. Royal Institution Proceedings 14: 524-538, 1895a.

    Google Scholar 

  • Lord Rayleigh. The Refraction and Viscosity of Argon and Helium. Chemical News 72: 152, 1895b.

    Google Scholar 

  • Lord Rayleigh and William Ramsay. Argon, a New Constituent of the Atmosphere. Philosophical Transactions of the Royal Society 186A: 187-241, 1895.

    Google Scholar 

  • C.J. Reed. A Prediction of the Discovery of Argon. Chemical News 71: 213-215, 1895.

    Google Scholar 

  • J. Emerson Reynolds. Argon and the Periodic System. Nature 51: 486-487, 1895.

    Google Scholar 

  • Eric R. Scerri and John Worrall. Prediction and the Periodic Table. To appear in Studies in History and Philosophy of Science.

  • William Sedgwick. The Existence of an Element without Valency of the Atomic Weight of 'Argon' Anticipated before the Discovery of 'Argon' by Lord Rayleigh and Prof. Ramsay. Chemical News 71: 139-140, 1895.

    Google Scholar 

  • J.W. van Spronsen. The Periodic System of Chemical Elements: A History of the First Hundred Years. Elsevier, Amsterdam, pp. 246-259, 1969.

    Google Scholar 

  • G. Johnstone Stoney. Argon — a Suggestion. Chemical News 71: 67-68, 1895.

    Google Scholar 

  • F. Sherwood Taylor. The Work of Sir William Ramsay; He Discovered Five New Elements in Six Years. American Scientist 41: 449-452, 1953.

    Google Scholar 

  • Julius Thomsen. Über die mutmassliche Gruppe inaktiver Elemente. Zeitschrift für anorganische Chemie 9: 283-288, 1895 (translated as On the Conjectural Group of Inactive Elements. Chemical News 77: 120-121, 1898).

    Article  Google Scholar 

  • Morris W. Travers. The Discovery of the Rare Gases. Edward Arnold, London, 1928.

    Google Scholar 

  • Morris W. Travers. A Life of Sir William Ramsay, K.C.B., F.R.S. Edward Arnold, London, 1956.

    Google Scholar 

  • Mary Elvira Weeks and Henry M. Leicester. Discovery of the Elements, 7th edition. Journal of Chemical Education, Easton, PA, 1968.

  • John H. Wolfenden. The Noble Gases and the Periodic Table: Telling it like it Was. Journal of Chemical Education 46: 569-567, 1969.

    Article  Google Scholar 

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  1. Le Moyne College, 1419 Salt Springs Road, Syracuse, NY, 13214-1399, USA

    Carmen J. Giunta

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Giunta, C.J. Argon and the Periodic System: the Piece that Would not Fit. Foundations of Chemistry 3, 105–128 (2001). https://doi.org/10.1023/A:1011464516139

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