The fundamental concept of structured chemical system has been introduced and analysed in this paper. This concept, as in biology but not in physics, is very important in chemistry. In fact, the main chemical concepts (molecule and compound) have been identified as systemic concepts and their use in chemical explanation can only be justified in this approach. The fundamental concept of “environment” has been considered and then the system concept in mechanics, chemistry and biology. The differences and (...) the analogies between the use of the systemic approach in these disciplines have been analyzed and correlated to the general problem of reductionism and complexity perspectives. The inanimate–animate dichotomy can be reconsidered in this new approach. Since the chemical systemic concepts of molecule and compound can be dated to the nineteenth century, chemistry can be considered the first true systemic science and its historical evolution can be a model for other sciences (such as the humanities) where the systemic concepts are important. (shrink)

SummaryFaraday's concept of force is described by six assumptions. These specify a concept that is quite distinct from ‘mechanical’ conceptions of his contemporaries and interpreters. Analysis of the role of these assumptions clarifies Faraday's weighting of experimental evidence and shows how closely-linked Faraday's chemistry and physics were to his theology. It is argued that Faraday was unable to secularize his concept of force by breaking the ties between his physics and his theology of nature. Examination of his basic assumptions (...) also explains Faraday's failure to quantify his principle of conservation of force, his rejection of mechanical concepts of force and energy, and his early attempt to develop a wave-model for the conversion and transmission of electricity, magnetism, light and heat. (shrink)

If nature is by definition the object of the natural sciences, then the dichotomy ‘natural’ versus ‘chemical’, held by both chemists and nonchemists, suggests an idiosyncrasy of chemistry. The first part of the paper presents a selective historical analysis of the main notions of nature in chemistry, as developed in early Christian views of chemical crafts, alchemy, iatrochemistry, mechanical philosophy, organic chemistry, and contemporary drug research. I argue that the dichotomy as well as quasi-moral judgments of (...) chemistry have been based on static and teleological notions of nature throughout history and that chemists, unlike physicists, have neglected the dynamic notion of nature. The second part provides a philosophical criticism of the former notions and argues for the latter as well as for an explicit discourse about values in chemistry.Author Keywords: History and philosophy of chemistry; Notion of nature; Alchemy; Mechanical philosophy; Synthetic organic chemistry; Contemporary drug research. (shrink)

“A millennium has gone by since the idea of the relationship of all things, the chain of causes was born. A comparison of the meaning of what we call causes throughout the history of human thinking could give us, no doubt, a conclusive epistemology.”.

We can distinguish ‘mechanical’ in the strict sense of the mechanical philosophers from ‘mechanical’ in the common sense. My claim is that Boyle's experimental science owed nothing to, and offered no support for, the mechanical philosophy in the strict sense. The attempts by my critics to undermine my case involve their interpreting ‘mechanical’ in something like the common sense. I certainly accept that Boyle's experimental science was productively informed by mechanical analogies, where ‘mechanical’ is interpreted in a common sense. But (...) this leaves my original claim untouched and, in the main, unchallenged.Keywords: Boyle; Mechanism; Mechanical philosophy; Corpuscular philosophy; Reductionism. (shrink)

Differing views on reduction are briefly reviewed and a suggestion is made for a working definition of 'approximate reduction'. Ab initio studies in quantum chemistry are then considered, including the issues of convergence and error bounds. This includes an examination of the classic studies on CH2 and the recent work on the Si2C molecule. I conclude that chemistry has not even been approximately reduced.

Chemists take mechanisms to be an important way of explaining chemical change. I examine the usefulness of the mechanism approach in the recent philosophical literature in explicating the explanatory use of mechanisms by organic chemists. I argue that chemists consider a mechanism to be explanatory because it accounts for the “dynamic process of bringing about” (Tabery 2004 , 10) chemical change. For chemists, mechanisms are causal explanations based on interventions that show “how some possibilities depend on others” (Woodward 2003 , (...) 375). Only possibilities are achievable because chemists face a number of challenges when they explain by means of a mechanism. †To contact the author, please write to: Department of Philosophy, Smith College, Northampton, MA 01063; e‐mail: [email protected]. (shrink)

Mechanisms are the how of chemical reactions. Substances are individuated by their structures at the molecular scale, so a chemical reaction is just the transformation of reagent structures into product structures. Explaining a chemical reaction must therefore involve different hypotheses about how this might happen: proposing, investigating and sometimes eliminating different possible pathways from reagents to products. One distinctive aspect of mechanisms in chemistry is that they are broken down into a few basic kinds of step involving the breaking (...) and making of bonds between atoms. This is necessary for chemical kinetics, the study of how fast reactions happen, and what affects it. It draws on G.N. Lewis’ identification of the chemical bond as involving shared electrons, which from the 1920s achieved the commensuration of chemistry and physics. The breaking or making of a bond just is the transfer of electrons, so a chemical bond on one side of an equation might be balanced on the other side by the appearance of a corresponding quantity of excess charge. A bond is understood to have been exchanged for a pair of electrons. Since reaction mechanisms rely on identities, doesn’t the establishment of a reaction mechanism explain away the chemical phenomena, showing that they are no more than the movement of charges and masses? In one sense yes: these mechanisms seem to involve a conserved-quantity conception of causation. But in another sense no: the ‘lower-level’ entities can do what they do only when embedded in higher-level organisation or structure. There need be no threat of reduction. (shrink)

The strength and defects of wave mechanics as a theory of chemistry are critically examined. Without the secondary assumption of wave–particle duality, the seminal equation describes matter waves and leaves the concept of point particles undefined. To bring the formalism into line with the theory of special relativity, it is shown to require reformulation in hypercomplex algebra that imparts a new meaning to electron spin as a holistic spinor, eliminating serious current misconceptions in the process. Reformulation in the (...) curved space–time of general relativity requires the recognition of nonlinear effects that invalidate the practice of linear combination of atomic orbitals, ubiquitous in quantum chemistry, and redefines the electron as a nondispersive wave packet, or soliton. (shrink)

In 2006, Perruchet and Pacton (2006) asked whether implicit learning and statistical learning represent two approaches to the same phenomenon. This article represents an important follow‐up to their seminal review article. As in the previous paper, the focus is on the formation of elementary cognitive units. Both approaches favor different explanations on what these units consist of and how they are formed. Perruchet weighs up the evidence for different explanations and concludes with a helpful agenda for future research.

This paper is divided in four parts. In the first part we introduce the method of internal critique of philosophical theories by examination of their external consistency with scientific theories. In the second part two metaphysical and one epistemological postulate of Wittgenstein's Tractatus are made explicit and formally expressed. In the third part we examine whether Tractarian metaphysical and epistemological postulates (the independence of simple states of affairs, the unique mode of their composition, possibility of complete empirical knowledge) are externally (...) consistent with the theory of quantum mechanics. The result of the inquiry is negative: Tractarian postulates ought to be be revised. Relying on the result we approach the question of the empirical character of logic in the fourth part. The description of theoretical transformations of the notion of disjunction, in its ontological, epistemological, and logical sense, is a common element of in all parts of the text. The conjecture on the existence of different types of disjunctive connectives in the language of quantum mechanics concludes the paper. (shrink)

In the context of theories of the connection between mind and brain, physicalism is the demand that all is basically purely physical. But the conception of “physical” embodied in this demand is characterized essentially by the properties of the physical that hold in classical physical theories. Certain of those properties contradict the character of the physical in quantum mechanics, which provides a better, more comprehensive, and more fundamental account of phenomena. It is argued that the difficulties that have plagued (...) physicalists for half a century, and that continue to do so, dissolve when the classical idea of the physical is replaced by its quantum successor. The argument is concretized in way that makes it accessible to non-physicists by exploiting the recent evidence connecting our conscious experiences to macroscopic measurable synchronous oscillations occurring in wellseparated parts of the brain. A specific new model of the mind-brain connection that is fundamentally quantum mechanical but that ties conscious experiences to these macroscopic synchronous oscillations is used to illustrate the essential disparities between the classical and quantum notions of the physical, and in particular to demonstrate the failure in the quantum world of the principle of the causal closure of the physical, a failure that goes beyond what is entailed by the randomness in the outcomes of observations, and that accommodates the efficacy in the brain of conscious intention. (shrink)

Although during the last decades the philosophy of chemistry has greatly extended its thematic scope, the main difficulties appear in the attempt to link the chemical description of atoms and molecules and the description supplied by quantum mechanics. The aim of this paper is to analyze how the difficulties that threaten the continuous conceptual link between molecular chemistry and quantum mechanics can be overcome or, at least, moderated from the perspective of BM. With this purpose, in (...) “The quantum-mechanical challenges” section the foundational incompatibility between chemical and SQM descriptions will be briefly recalled. “Bohmian mechanics” section will be devoted to explain the main features of BM. In “Empirical equivalence and underdetermination” section, the consequences of the empirical equivalence between SQM and BM will be discussed. Finally, in the Conclusion, we will stress the scope of the obtained conclusions and the philosophical difficulties that still remain even after adopting BM for foundational purposes. (shrink)

Nonobjectivity of physical properties enters physics with the standard interpretation of quantum mechanics (QM), and a number of paradoxes of this theory follow from it. It seems, however, based on sound physical arguments (double slit experiment, Heisenberg's principle, Bell–Kochen–Specker theorem, etc.), so that most physicists think that avoiding it is impossible. We discuss these arguments here and show that they can be criticized from a physical viewpoint. Our criticism proves that nonobjectivity must be considered an epistemological choice rather than (...) an unavoidable feature of QM, so that an objective interpretation of QM is not a priori impossible, which justifies our attempt at providing it in some previous papers. This interpretation is based on a classical language in which the language of the standard interpretation (Quantum Logic) is embedded as a subset of statements that are directly testable according to QM. (shrink)

This paper analyses Richard Bader’s ‘operational’ view of quantum mechanics and the role it plays in the the explanation of chemistry. I argue that QTAIM can partially be reconstructed as an ‘austere’ form of quantum mechanics, which is in turn committed to an eliminative concept of reduction that stems from Kemeny and Oppenheim. As a reductive theory in this sense, the theory fails. I conclude that QTAIM has both a regulatory and constructive function in the theories of (...) chemistry. (shrink)

Most contemporary chemists consider quantum mechanics to be the foundational theory of their discipline, although few of the calculations that a strict reduction would seem to require have ever been produced. In this essay I discuss contemporary algebraic and diagrammatic representations of molecular systems derived from quantum mechanical models, specifically configuration interaction wavefunctions for ab initio calculations and molecular orbital energy diagrams. My aim is to suggest that recent dissatisfaction with reductive accounts of chemical theory may stem from both (...) the inability of standard accounts of reduction to incorporate the diverse forms of representation found in chemical practice and our philosophical predilection to analyze all connections between theories in terms of logical reduction. (shrink)

Although during the last decades the philosophy of chemistry has greatly extended its thematic scope, the main difficulties appear in the attempt to link the chemical description of atoms and molecules and the description supplied by quantum mechanics. The aim of this paper is to analyze how the difficulties that threaten the continuous conceptual link between molecular chemistry and quantum mechanics can be overcome or, at least, moderated from the perspective of BM. With this purpose, in (...) “The quantum-mechanical challenges” section the foundational incompatibility between chemical and SQM descriptions will be briefly recalled. “Bohmian mechanics” section will be devoted to explain the main features of BM. In “Empirical equivalence and underdetermination” section, the consequences of the empirical equivalence between SQM and BM will be discussed. Finally, in the Conclusion, we will stress the scope of the obtained conclusions and the philosophical difficulties that still remain even after adopting BM for foundational purposes. (shrink)

The neobehaviorist Clark L. Hull and his disciple Kenneth Spence shared in common many views on the nature of science and the role of theories in psychology. However, a telling exchange in their correspondence of the early 1940s reveals a disagreement over the nature of intervening variables in behavior theory. Spence urged Hull to abandon his interpretations of intervening variables in terms of physiological models in favor of positivistic, purely mathematical interpretations that conflicted with Hull's mechanistic explanatory aims and ontological (...) commitment to materialism. This dispute is set against the background of similar disputes in physics, and the origins of Hull's and Spence's divergent views on theoretical explanation are described. (shrink)

Although during the last decades the philosophy of chemistry has greatly extended its thematic scope, the main difficulties appear in the attempt to link the chemical description of atoms and molecules and the description supplied by quantum mechanics. The aim of this paper is to analyze how the difficulties that threaten the continuous conceptual link between molecular chemistry and quantum mechanics can be overcome or, at least, moderated from the perspective of BM. With this purpose, in (...) “The quantum-mechanical challenges” section the foundational incompatibility between chemical and SQM descriptions will be briefly recalled. “Bohmian mechanics” section will be devoted to explain the main features of BM. In “Empirical equivalence and underdetermination” section, the consequences of the empirical equivalence between SQM and BM will be discussed. Finally, in the Conclusion, we will stress the scope of the obtained conclusions and the philosophical difficulties that still remain even after adopting BM for foundational purposes. (shrink)

The social contracts theory claims that, in social exchange circumstances, human reasoning is not necessarily led by logic, but by certain evolved mental mechanisms that are useful for catching offenders. An emblematic experiment carried out with the intention to prove this thesis is the first experiment described by Fiddick, Cosmides, and Tooby in their paper of 2000. Lopez Astorga has questioned that experiment claiming that its results depend on an underlying conditional logical form not taken into account by Fiddick, Cosmides, (...) and Tooby. In this paper, I propose an explanation alternative to that of Lopez Astorga, which does not depend on logical forms and is based on the mental models theory. Thus, I conclude that this other alternative explanation is one more proof that the experiment in question does not demonstrate the fundamental thesis of the social contracts theory. (shrink)

There is little fear that the concept of motivational bias as proposed by Mele is likely to dampen the current academic ferment (see Mele's Introduction) with respect to self-deception for several reasons: (a) like philosophy, science has more recently abandoned the heuristic of a rational human mind; (b) the concept is parsimonious, applicable to many research topics other than self-deception, and, therefore, scientifically serviceable; (c) as a proximal mechanism it addresses process rather than function, that is, how rather than why (...) questions; (d) it is not as interesting a question as why there is a high prevalence of “real” self-deception (i.e., “garden-variety self-deception” as described by Mele, see sect. 6); and (e) a more penetrating issue is whether “real” self-deception is adaptive. (shrink)

When science of the 20th century is spoken of in opposition to that of the 19th century, a particularly characteristic attribute is often cited: namely, that since the time of Galileo and Newton the task of science has been to explain everything mechanistically. By analogy the world was to be conceived as a great machine. But the theories of the 20th century, above all the relativity and quantum theories, caused a revolution in science. It is seen today that nature can (...) be described and understood not ‘mechanistically’ but only through abstract mathematical formulas. The world is no longer a machine but a mathematical formula. (shrink)

Mathematical physics works by representing the contents of the world and the world’s dynamical changes by the components of some mathematical structure and the transformations one can impose on these components. Quite rightly, philosophers of science have concentrated much attention on trying to understand how physicists arrive at the appropriate transformational rules to represent dynamical evolution in the world, that is, on how they find the correct laws of nature. But the preliminary problem, how to choose the appropriate mathematical representatives (...) for the things of the world and their states of being, has received, perhaps, less attention than it deserves. (shrink)

Charlotte Werndl and Roman Frigg discuss the relationship between the Boltzmannian and Gibbsian framework of statistical mechanics, addressing, in particular, the question when equilibrium values calculated in both frameworks agree. This note points out conceptual confusions that could arise from their discussion, concerning, in particular, the authors’ use of “Boltzmann equilibrium.” It also clarifies the status of the Khinchin condition for the equivalence of Boltzmannian and Gibbsian equilibrium predictions and shows that it follows, under the assumptions proposed by Werndl (...) and Frigg, from standard arguments in probability theory. (shrink)

By moving away from the traditional reductionist reading of the quantum theory of atoms in molecules, in this paper we analyze the role played by QTAIM in the relationship between molecular chemistry and quantum mechanics from an emergentist perspective. In particular, we show that such a relationship involves two steps: an intra-domain emergence and an inter-domain emergence. Intra-domain emergence, internal to quantum mechanics, results from the fact that the electron density, from which all the other QTAIM’s concepts (...) are defined, arises from the wavefunction as a coarse-grained magnitude. Inter-domain emergence involves an analogical link, a mapping, between QTAIM’s entities, such as topological atoms and bond paths, and the entities that populate the molecular-chemistry domain, such as chemical atoms and chemical bonds. (shrink)

Most contemporary chemists consider quantum mechanics to be the foundational theory of their discipline, although few of the calculations that a strict reduction would seem to require have ever been produced. In this essay I discuss contemporary algebraic and diagrammatic representations of molecular systems derived from quantum mechanical models, specifically configuration interaction wavefunctions for ab initio calculations and molecular orbital energy diagrams. My aim is to suggest that recent dissatisfaction with reductive accounts of chemical theory may stem from both (...) the inability of standard accounts of reduction to incorporate the diverse forms of representation found in chemical practice and our philosophical predilection to analyze all connections between theories in terms of logical reduction. (shrink)

This thesis investigates the epistemological and metaphysical relations between chemistry and quantum mechanics. These relations are examined with respect to how chemistry and quantum mechanics each describe a single inert molecule. A review of how these relations are understood in the literature shows that there is a proliferation of positions which focus on how chemistry is separate from quantum mechanics. This proliferation is accompanied by a tendency within the philosophy of chemistry community to (...) connect the legitimacy of the field with the autonomy of chemistry. First, it is argued that this connection should not be made. Secondly, it is argued that chemistry and quantum mechanics are unified in accordance with Harold Kincaid’s model of non-reductive unity because the two theories exhibit particular epistemic and metaphysical interconnections. Thirdly, a metaphysical account is examined which is incompatible with Kincaid’s model of unity; namely strong emergence as understood by Robin Hendry. According to Hendry, the structure of a single inert molecule strongly emerges from its quantum mechanical entities in the sense that there is downward causation. However, Hendry’s defense of this account faces certain problems. Moreover, the putative empirical evidence for his understanding of strong emergence can be explained without invoking strong emergence. This is shown by considering how quantum mechanics assumes an idealized understanding of a molecule’s stability and structure. In the light of the philosophical literature on idealizations, this idealization can be interpreted in two different ways, both of which explain why quantum mechanics describes the structure of a single molecule the way it does, without assuming strong emergence in Hendry’s sense. Each interpretation has philosophical implications regarding the nature of chemical properties, and the relation of chemistry and quantum mechanics. These implications are consistent with Kincaid’s model of unity and thus further support chemistry’s unity with quantum mechanics (as per Kincaid). (shrink)

This book is a treatise on time and on background independence in physics. It first considers how time is conceived of in each accepted paradigm of physics: Newtonian, special relativity, quantum mechanics (QM) and general relativity (GR). Substantial differences are moreover uncovered between what is meant by time in QM and in GR. These differences jointly source the Problem of Time: Nine interlinked facets which arise upon attempting concurrent treatment of the QM and GR paradigms, as is required in (...) particular for a background independent theory of quantum gravity. A sizeable proportion of current quantum gravity programs - e.g. geometrodynamical and loop quantum gravity approaches to quantum GR, quantum cosmology, supergravity and M-theory - are background independent in this sense. This book's foundational topic is thus furthermore of practical relevance in the ongoing development of quantum gravity programs. This book shows moreover that eight of the nine facets of the Problem of Time already occur upon entertaining background independence in classical (rather than quantum) physics. By this development, and interpreting shape theory as modelling background independence, this book further establishes background independence as a field of study. Background independent mechanics, as well as minisuperspace (spatially homogeneous) models of GR and perturbations thereabout are used to illustrate these points. As hitherto formulated, the different facets of the Problem of Time greatly interfere with each others' attempted resolutions. This book explains how, none the less, a local resolution of the Problem of Time can be arrived at after various reconceptualizations of the facets and reformulations of their mathematical implementation. Self-contained appendices on mathematical methods for basic and foundational quantum gravity are included. Finally, this book outlines how supergravity is refreshingly different from GR as a realization of background independence, and what background independence entails at the topological level and beyond. (shrink)

Chemistry and dynamics are closely related in G.W. Leibniz's thinking, from the corpuscularism of his youth to the theory of conspiracy movements that he proposes in his later years. Despite the importance of chemistry and chemical thought in Leibniz's philosophy, interpreters have not paid enough attention to this subject, especially in the recent decades. This work aims to contribute to filling this gap in Leibnizian studies. In this first part of the work I will expose the theory of (...) matter that the young Leibniz conceives under the influence of chemical corpuscularism. Leibniz uses R. Boyle's interpretation of the Aristotelian idea of form in order to give an explanation of the unity and cohesion of bodies. As opposed to the Cartesians, Leibniz puts forth the idea of a dependence between the variables of extension, movement and figure, without losing analytical clarity and with the aim of extending the explanatory power of physics to natural phenomena difficult to approach by Cartesian mechanics. (shrink)

Harold Kincaid in Individualism and the Unity of Science postulates a model of unity-without-reduction in order to accurately describe the relation between individualism and macroeconomics. I present this model and apply it to the description of the relation between chemistry and quantum mechanics. I argue that, when it comes to the description of molecular structure, chemistry and quantum mechanics are unified in Kincaid’s sense. Specifically, the two disciplines contribute to the formation of a unified body of (...) knowledge with respect to molecular structure. (shrink)