Samuel Lytler Metcalfe was an American chemist and physician who wrote a voluminous work, Caloric Its Mechanical Chemical and Vital Agencies in the Phenomena of Nature ; attempting to account for all natural phenomena in terms of caloric. The book came out at the time when the concept of caloric was being gradually discarded and the law of conservation of energy was about to appear. Metcalfe was convinced that caloric would be the key to unlock the (...) secrets of nature; in order to develop the practical implications of his views he made research trips twice to England , and there he completed Caloric. (shrink)

Professional historians of science generally recognize the importance of Lavoisier's theory of heat. However, it commonly receives scant attention in the historical treatment of his chemical theories except perhaps as an example illustrating his conservatism and giving the impression that the caloric theory, although perhaps important in the development of ideas on the nature of heat, is independent of and bears little relationship to his general chemistry or is incidental to an understanding of that chemistry. An examination (...) of Lavoisier's writings suggests that the caloric theory is not merely a milestone in the development of physics; and rather than an omittable appendage, his concept of heat forms an integral part of his chemical system and plays a central, necessary role in his oxidation theory in particular. The purpose of this paper is to give a general description of Lavoisier's ideas on the nature and action of heat, the origin of these ideas, their development, and their relation to his general chemistry, pointing out his conservatism as well as his innovations. (shrink)

I began this study with Laudan's argument from the pessimistic induction and I promised to show that the caloric theory of heat cannot be used to support the premisses of the meta-induction on past scientific theories. I tried to show that the laws of experimental calorimetry, adiabatic change and Carnot's theory of the motive power of heat were independent of the assumption that heat is a material substance, approximately true, deducible and accounted for within thermodynamics.I stressed that (...) results and were known to most theorists of the caloric theory and that result was put forward by the founders of the new thermodynamics. In other words, the truth-content of the caloric theory was located, selected carefully, and preserved by the founders of thermodynamics.However, the reader might think that even if I have succeeded in showing that laudan is wrong about the caloric theory, I have not shown how the strategy followed in this paper can be generalised against the pessimistic meta-induction. I think that the general strategy against Laudan's argument suggested in this paper is this: the empirical success of a mature scientific theory suggests that there are respects and degrees in which this theory is true. The difficulty for — and and real challenge to — philosophers of science is to suggest ways in which this truth-content can be located and shown to be preserved — if at all — to subsequent theories. In particular, the empirical success of a theory does not, automatically, suggest that all theoretical terms of the theory refer. On the contrary, judgments of referential success depend on which theoretical claims are well-supported by the evidence. This is a matter of specific investigation. Generally, one would expect that claims about theoretical entities which are not strongly supported by the evidence or turn out to be independent of the evidence at hand, are not compelling. For simply, if the evidence does not make it likely that our beliefs about putative theoretical entities are approximately correct, a belief in those entities would be ill-founded and unjustified. Theoretical extrapolations in science are indespensable, but they are not arbitrary. If the evidence does not warrant them I do not see why someone should commit herself to them. In a sense, the problem with empricist philisophers is not that they demand that theoretical beliefs must be warranted by evidence. Rather, it is that they claim that no evidence can warrant theorretical beliefs. A realist philosopher of science would not disagree on the first, but she has good grounds to deny the second.I argued that claims about theoretical entities which are not strongly supported by the evidence must not be taken as belief-worthy. But can one sustaon the more ambitious view that loosely supported parts of a theory tend to be just those that include non-referring terms? There is an obvious excess risk in such a generalisation. For there are well-known cases in which a theoretical claim was initially weakly supported by the evidence. (shrink)

Research on thermal “black-body” radiation played an essential role in the origin of the quantum theory at the beginning of the twentieth century. This is a well-known fact, but historians of science up to now have not generally recognized that studies of radiant heat were also important in an earlier episode in the development of modern physics: the transition from caloric theory to thermodynamics. During the period 1830–50, many physicists were led by these studies to accept a (...) “wave theory of heat”, although this theory subsequently faded into obscurity. (shrink)

A popular and plausible response against Laudan's “pessimistic induction” has been what I call “preservative realism,” which argues that there have actually been enough elements of scientific knowledge preserved through major theory‐change processes, and that those elements can be accepted realistically. This paper argues against preservative realism, in particular through a critical review of Psillos's argument concerning the case of the caloric theory of heat. Contrary to his argument, the historical record of the caloric theory (...) reveals that beliefs about the properties of material caloric, rejected by subsequent theories, were indeed central to the successes of the caloric theory. Therefore caloric remains a favorable case for Laudan. Further, I argue that even confirmed cases of preservation do not warrant an inference to truth. (shrink)

The pessimistic induction argument, most often associated with Larry Laudan, is now widely considered to be one of the main obstacles for realism. Put simply, the argument holds that since past predictively successful scientific theories have eventually been discarded, we have inductive evidence that our current theories will also be discarded one day. More precisely, Laudan undermines the inference from the explanatory and predictive success of a theory to its approximate truth and referential success. This paper criticises a particular (...) kind of realist reply to Laudan. (shrink)

In scientific realist eyes we are only warranted to assert that a theory is true or approximately true if that theory enjoys considerable explanatory and predictive success. The most well known challenge to this claim, the pessimistic meta-induction, holds that the history of science is replete with successful theories that are now considered false. In effect, this challenge raises doubts about the reliability of inferences from explanatory and predictive success to (approximate) truth. The main realist reaction has been (...) to argue that upon closer scrutiny the historical record can be reconciled with scientific realism. When a successful theory is abandoned, not all of its components are discarded but only those that are inessential or idle for the theory’s success. Their abandonment is thus inconsequential for the realist. In this talk I consider what the modern kinetic theory of heat managed to salvage from the outdated caloric theory and whether the inter-theoretic relations between the two theories support a realist view of science. (shrink)

William Thomson published between 1849 and 1852 three influential papers on the theory of heat. However, historians of science have already called attention to Thomson's difficulties in reconciling a principle formulated by James Prescott Joule with another principle formulated by Nicolas Leonard Sadi Carnot, and to errors Thomson made in his calculations. In the meantime, Rudolf Julius Emmanuel Clausius reconciled the two principles, and in 1854 he derived an expression for Carnot's principle. The author and collaborators have shown elsewhere (...) that it was fundamental to Clausius' reasoning that he took to its ultimate consequence the meaning of Carnot's principle as a ‘recovery’ condition. Thomson somehow let the meaning of ‘recovery’ escape him. Therefrom came his troubles. He seems to have been so obsessed by his initial difficulties that he put the emphasis on irreversibility and on conservation of energy, missing ‘all the rest’. (shrink)

Imagine you live in 1823 and you are about to design an advanced course on the theory of heat. About fifty years ago, Lavoisier and Laplace had posited caloric as a material substance—an indestructible fluid of fine particles—which was taken to be the cause of heat and in particular, the cause of the rise of temperature of a body, by being absorbed by the body. No doubt, you rely on the best available theory, which is the (...) class='Hi'>caloric theory. In particular, meticulous and knowledgeable as you are, you rely on the best of the best: Laplace’s advanced account of the caloric theory of heat, with all its sophistication, detail and predictive might. You really believe that the best science teaching should be based on the best theories that are available. But you also believe that the best theory that is available is not really the best unless it has a claim to truth (or truthlikeness, or partial truth and the like). For what is the point of teaching a theory about the deep structure of the world unless it does say something or other about this deep structure? The course goes really well. Your notes are impressive. They are soon turned into a textbook with lots of explanatory detail and fancy calculations. Alas! The world does not co-operate. There are no calorific particles among the things there are in it. Heat is destroyed when work is produced. The advanced theory is challenged by alternative theories, anomalies and failed predictions. There is agony, but in your lifetime, the caloric theory gets superseded and is left discredited in the wasteland of false theories. Decades come by. You are not around anymore. Your grandchildren go to school and.. (shrink)

Although theories that examine direct links between behavior and brain remain incomplete, it is known that brain expansion significantly correlates with caloric and oxygen demands. Therefore, one of the principles governing evolutionary cognitive neuroscience is that cognitive abilities that require significant brain function (and/or structural support) must be accompanied by significant fitness benefit to offset the increased metabolic demands. One such capacity is self-awareness (SA), which (1) is found only in the greater apes and (2) remains unclear in terms (...) of both cortical underpinning and possible fitness benefit. In the current experiment, transcranial magnetic stimulation (TMS) was applied to the prefrontal cortex during a spatial perspective-taking task involving self and other viewpoints. It was found that delivery of TMS to the right prefrontal region disrupted self-, but not other-, perspective. These data suggest that self-awareness may have evolved in concert with other right hemisphere cognitive abilities. (shrink)

According to the antirealist argument known as the pessimistic induction, the history of science is a graveyard of dead scientific theories and abandoned theoretical posits. Support for this pessimistic picture of the history of science usually comes from a few case histories, such as the demise of the phlogiston theory and the abandonment of caloric as the substance of heat. In this article, I wish to take a new approach to examining the ‘history of science as a graveyard (...) of theories’ picture. Using JSTOR Data for Research and Springer Exemplar, I present new lines of evidence that are at odds with this pessimistic picture of the history of science. When rigorously tested against the historical record of science, I submit, the pessimistic picture of the history of science as a graveyard of dead theories and abandoned posits may turn out to be no more than a philosophers’ myth. (shrink)

In 1824 Sadi Carnot published Réflexions sur la Puissance Motrice du Feu in which he founded almost the entire thermodynamics theory. Two years after his death, his friend Clapeyron introduced the famous diagram PV for analytically representing the famous Carnot’s cycle: one of the main and crucial ideas presented by Carnot in his booklet. Twenty-five years later, in order to achieve the modern version of the theory, Kelvin and Clausius had to reject the caloric hypothesis, which had (...) influenced a few of Carnot’s arguments. Relying on the possibility of studying the history of science by means of logical investigation, in this paper I shall propose an historical/epistemological research on Sadi Carnot’s original thermodynamics theory in which the French scientist presents more than two principles, all of which are expressed by double negated sentences (generally speaking) within non-classical logic. (shrink)

During the years 1814–1819, William Higgins, an Irish chemist who worked at the Dublin Society, claimed he had anticipated John Dalton in developing the atomic theory and insinuated that Dalton was a plagiarist. This essay focuses not on William Higgins, but on his uncle Bryan Higgins, a well-known chemist of his day, who had developed his own theories of caloric and chemical combination, similar in many respects to that of Dalton. New evidence is first introduced addressing Bryan's disappearance (...) from the scientific community after 1803. In his later years, Bryan apparently suffered from a condition resulting in a decline in his mental health, which explains why he never lodged any priority claims of his own against Dalton, or defended those of his nephew. Dalton's mention of Bryan's name in Part II ofA New System of Chemical Philosophy, his laboratory notebook entries, and a fresh look at his correspondence with chemist Thomas Charles Hope indicate that Dalton adopted a Higgins-like caloric model in 1803. Together these factors provide evidence to support the argument that Dalton learned of Bryan's theories via a meeting he had with William Allen on 10 July 1803. Existing evidence related to the origin of the atomic theory is worthy of re-examination in light of Dalton's possible prior knowledge of Bryan's work. (shrink)

This book is intended as a reference source of “universal scientific laws, physical principles, viable theories, and testable hypotheses” from ancient times to the present. Robert Krebs states that he includes only the physical and biological sciences, including geology, but in fact there are also several mathematical and logical entries ranging from the Greeks to Gödel. The book contains over four hundred entries, in alphabetical order, averaging less than a page each, plus a glossary of nearly four hundred technical terms. (...) Evidently, it is intended as a library reference for a general audience. It does not seem to be directed toward professional historians of science. The author is a retired university science administrator in the health sciences field.Opening the book at random, I find four entries on the facing pages: “Carnot's Theories of Thermodynamics,” “Caspersson's Theory of Protein Synthesis,” “Cassini's Hypothesis for Size of the Solar System,” and “Cavendish's Theories and Hypothesis.” It is hard to know what the principle of selection is, other than comprehensive coverage. But although it is impressive, the coverage is spotty. The famous story of Adams, Leverrier, and Neptune is not included, for example—perhaps because no new law is involved.To a historical scholar, such a project has obvious pitfalls; I will list some of them. First, it is whiggish in selecting and evaluating the entries from our standpoint and in often omitting now‐discredited content. For example, the entry on Carnot does not mention caloric, although it does mention the model of water flowing over a waterwheel. The book encourages the idea that discoveries and other major results are more or less punctiform, the achievements of particular individuals at particular times. To be fair, in his introduction Krebs does describe science as an ongoing, self‐correcting process in which “laws” sometimes turn out to be false or to need correction. The book is historically uncritical, since it accepts at face value that eponymous results were actually achieved by the person celebrated in the name. The entries are necessarily too brief to indicate much of the wider historical context, or even the technical context, in which the law or theory under discussion was developed. Krebs's statement of his intent, in the introduction to the volume, is theory centered and seems to take physics as a model, although in fact there are many entries from the biomedical sciences that do not neatly fit this model. The author's attempt to characterize his subject matter—scientific laws—is philosophically naïve. Finally, even if we leave aside the difficulty of making complex technical results accessible to a general audience in a very limited space, no single author can be expert enough to maintain a high standard throughout a volume of such scope. Krebs identifies no panel of expert consultants enlisted to check his entries.The entries that I sampled sometimes contained less‐than‐sharp formulations, inaccuracies, and even contradictions. For example, Krebs describes Aristotle, in cliché fashion, as a “philosopher” rather than as a “scientist concerned with observations and evidence” , but two paragraphs later it turns out that Aristotle based his account of spontaneous generation on observations! Krebs says that motion was self‐explanatory for Aristotle because things strive to reach their natural places. The entry on Euler mislabels his work on bodies moving with multiple degrees of freedom as the three‐body problem. Fermat's last theorem is said to remain unsolved, yet Krebs obviously prides himself on being up to date. The entry on Planck is historically inaccurate and physically misleading. And so on.For all that, I found the book rather interesting and useful. No reader leafing through it will fail to find this entry or that intriguing. Since the entries are short and discrete, the book makes good bedtime reading. And, given that the laws, principles, and effects are commonly called by these names, the book can serve as a source of general knowledge—but only as a starting point. Given the uneven quality, caveat lector! (shrink)

Having refuted the phlogiston theory, Lavoisier uses this second portion of his essay to expound his new theory of combustion, based on the oxygen principle. He gives a mechanistic account of thermodynamic phenomena in terms of a subtle fluid and its ability to penetrate porous bodies. He uses this hypothetical fluid to explain volume changes, heat capacity and latent heat. Beyond the three types of combustion that he distinguishes and defines, Lavoisier also explains other chemical sources of heat, (...) such as the heat of solution. (shrink)

A Critique of Localized Realism Abstract In an attempt to avert Laudan’s pessimistic induction, Worrall and Psillos introduce a narrower version of scientific realism. According to this version, which can be referred to as “localized realism”, realists need not accept every component in a successful theory. They are supposed only to accept those components that led to the theory’s empirical success. Consequently, realists can avoid believing in dubious entities like the caloric and ether. This paper examines and (...) critiques localized realism. It also scrutinizes Psillos’s historical study of the caloric theory of heat, which is intended to support localized realism. (shrink)

Historical case studies of scientific concepts are a useful medium for showing how scientific ideas originate and how they change over time. They are thus a useful tool for conveying knowledge about the nature of science. This paper focuses on the concepts of heat and temperature and discusses some issues related to choosing the content for a historical case study which incorporates not only nature of science perspectives but understandings related to what we know about the teaching and learning of (...) these concepts. The case study is designed for first-year university chemistry students as an introduction to their study of thermodynamics. The paper includes a general chemistry textbook analysis of the heat and temperature concepts and a discussion of the caloric theory of heat, thermometry, and a brief survey of how the energy concept transformed our understanding of heat and temperature. (shrink)

Although theories that examine direct links between behavior and brain remain incomplete, it is known that brain expansion significantly correlates with caloric and oxygen demands. Therefore, one of the principles governing evolutionary cognitive neuroscience is that cognitive abilities that require significant brain function (and/or structural support) must be accompanied by significant fitness benefit to offset the increased metabolic demands. One such capacity is self-awareness (SA), which (1) is found only in the greater apes and (2) remains unclear in terms (...) of both cortical underpinning and possible fitness benefit. In the current experiment, transcranial magnetic stimulation (TMS) was applied to the prefrontal cortex during a spatial perspective-taking task involving self and other viewpoints. It was found that delivery of TMS to the right prefrontal region disrupted self-, but not other-, perspective. These data suggest that self-awareness may have evolved in concert with other right hemisphere cognitive abilities. (shrink)

The hypothesis that foreseeable developments in interventions directed to forestall and to treat the disabilities of aging might result in the extension of the human lifespan may be further supported by the “evolutionary theory of aging.” Besides caloric restriction, several hormone supply or replacement strategies are considered to contrast the functional decline associated with aging. Hormone treatments may include growth hormone (GH), insulin‐like growth factor I (IGF‐I) signaling, dehydroepiandrosterone (DHEA), melatonin, testosterone, progesterone, and estrogen. In the 1990s, DHEA (...) was exalted as a possible candidate for the “fountain of youth.” Several experiments on animals have shown that DHEA is a multifunctional adrenal steroid with immune function enhancement, anti‐diabetic, anti‐cancer, and anti‐aging effects. The ethical questions concerning the extension of the lifespan belong to two distinct areas: the area of individual morality and the area of social morality. (shrink)

Realists have responded to challenges from the historical record of successful but ultimately rejected theories with what I call the selective confirmation strategy: arguing that only idle parts of past theories have been rejected, while truly success‐generating features have been confirmed by further inquiry. I argue first, that this strategy is unconvincing without some prospectively applicable criterion of idleness for theoretical posits, and second, that existing efforts to provide one either convict all theoretical posits of idleness (Kitcher) or stand refuted (...) by detailed consideration of the very examples (optical/electromagnetic ether, caloric fluid) to which they appeal (Psillos). I also argue that available avenues for improving on these proposals are unpromising. (shrink)

By focusing on the caloric composition of hunted prey species, optimal foraging research has shown that hunters usually make economically rational prey choice decisions. However, research by meat scientists suggests that the gustatory appeal of wildlife meats may vary dramatically. In this study, behavioral research indicates that Mayangna and Miskito hunters in Nicaragua inconsistently pursue multiple prey types in the optimal diet set. We use cognitive methods, including unconstrained pile sorts and cultural consensus analysis, to investigate the hypothesis that (...) these partial preferences are influenced by considerations of meat flavor. Native informants exhibit high agreement on the relative appeal of different meats. Given the absence of other noteworthy differences between spider monkeys (Ateles geoffroyi) and howler monkeys (Alouatta palliata), the unappealing flavor of howler monkeys seems to be a factor in the partial preference for this species. (shrink)

I deny that the world is fundamentally causal, deriving the skepticism on non-Humean grounds from our enduring failures to find a contingent, universal principle of causality that holds true of our science. I explain the prevalence and fertility of causal notions in science by arguing that a causal character for many sciences can be recovered, when they are restricted to appropriately hospitable domains. There they conform to a loose collection of causal notions that form a folk science of causation. This (...) recovery of causation exploits the same generative power of reduction relations that allows us to recover gravity as a force from Einstein's general relativity and heat as a conserved fluid, the caloric, from modern thermal physics, when each theory is restricted to appropriate domains. Causes are real in science to the same degree as caloric and gravitational forces. (shrink)

I deny that the world is fundamentally causal, deriving the skepticism on non-Humean grounds from our enduring failures to find a contingent, universal principle of causality that holds true of our science. I explain the prevalence and fertility of causal notions in science by arguing that a causal character for many sciences can be recovered, when they are restricted to appropriately hospitable domains. There they conform to loose and varying collections of causal notions that form folk sciences of causation. This (...) recovery of causation exploits the same generative power of reduction relations that allows us to recover gravity as a force from Einstein's general relativity and heat as a conserved fluid, the caloric, from modern thermal physics, when each theory is restricted to appropriate domains. Causes are real in science to the same degree as caloric and gravitational forces. (shrink)

The debate over foundationalism, the viewpoint that there exists some secure foundation upon which to build a system of knowledge, appears to have been resolved and the antifoundationalists have at least temporarily prevailed. From a firmly historical approach, the book traces the foundationalism/antifoundationalism controversy in the work of many important figures Animaxander, Aristotle and Plato, Augustine, Descartes, Hegel and Nietzsche, Habermas and Chisholm, and others throughout the history of philosophy. The contributors, Joseph Margolis, Ronald Polansky, Gary Calore, Fred and Emily (...) Michael, William Wurzer, Charlene Haddock Siegfried, Sandra B. Rosenthal, Kathleen Wallace, and the editors present well the diversity, interest, and roots of antifoundationalism. Tom Rockmore is Professor and Chairman in the Department of Philosophy at Duquesne University. Beth J. Singer is Professor of Philosophy at Brooklyn College of the City University of New York. (shrink)

For the last two decades a doctrine called ‘‘eliminative materialism’’ (or sometimes just ‘‘eliminativism’’) has been a major focus of discussion in the philosophy of mind. It is easy to understand why eliminativism has attracted so much attention, for it is hard to imagine a more radical and provocative doctrine. What eliminativism claims is that the intentional states and processes that are alluded to in our everyday descriptions and explanations of people’s mental lives and their actions are _myths_. Like the (...) gods that Homer invoked to explain the outcome of battles, or the witches that Inquisitors invoked to explain local catastrophes, they _do not exist_. According to eliminativists, there are no such things as beliefs or desires or hopes or fears or thoughts. These putative states and processes are the badly misguided posits of a seriously mistaken theory, just like phlogiston and caloric fluid and the luminiferous ether.¹. (shrink)

The purpose of this paper is to show how the degree of experimental validity of scientific procedures is crucially involved in determining two typical pragmatic modes in science, namely, the preservation of useful procedures and the disposal of useless ideas. The term 'pragmatic' will here be used following Schurz's characterisation of being internally pragmatic, as referring to that which proves useful for scientific or epistemic goals. The first part of the paper consists in a characterisation of the notion of experimental (...) validity. The second part is focused on several historical examples illustrating how the above pragmatic modes relate to the question of experimental validity. The Michelson-Morley experiment is presented as a case of a highly valid and useful experiment preserved through the development of different theories (like, on the one hand, the ether theory, upheld by Fitzgerald and Lorentz, and, on the other hand, Einstein's special theory of relativity). The concept of caloric will be discussed as an example of an idea that was discarded once it became useless, after heat was understood as a form of energy within the new frame provided by the kinetic theory of heat towards the middle of the 19th century. (shrink)

In lieu of an abstract, here is a brief excerpt of the content:Journal of the History of Philosophy 39.4 (2001) 467-489 [Access article in PDF] "By the Things Themselves":Eudaimonism, Direct Acquaintance, and Illumination in Augustine's De Magistro 1 Michael Mendelson 1. The Eudaimonistic Interlude It comes as a surprise. Two-thirds of the way through De Magistro, amid a torturous and at times obscure discussion of the nature of language, Augustine pauses to provide Adeodatus, his son and interlocutor, with what seems (...) a rather odd digression:...with so many detours, it's difficult to say at this point where you and I are trying to get to! Maybe you think we're playing around and diverting the mind from serious matters by some little puzzles that seem childish, or that we're pursuing some result that is only small or modest....Though we do perhaps play around, this should itself not be regarded as childish. Nor are we thinking about small and modest goods. Yet if I were to say that there is a happy and everlasting life, and I want us to be led there under the guidance of God (namely by Truth Himself) by stages that are suitable to our weak steps, I'm afraid I might seem laughable for having set out on such a long journey by considering signs rather than the things themselves that are signified. So then, you'll pardon me if I play around with you at first—not for the sake of playing around, but to exercise the mind's strength and sharpness, with which we're [End Page 467] able not only to withstand but also to love the heat and light of that region where the happy life is. 2One is left wondering—if one pauses long enough to wonder at all—what exactly the preceding tightly woven and technical discussion of signification has to do with the "heat" (calor) and the "light" (lux) of the "region" (regio) where the "happy life" (beata vita) is to be found. Indeed, even the passage itself acknowledges the ostensible obliqueness of the connection without doing very much to highlight its nature.It is not surprising that readers of De Magistro often overlook this eudaimonistic interlude in favor of the more prominent and arresting difficulties with which the text confronts us. There is, after all, the somewhat awkward view of language which underlies the entire discussion, and there is also what seems to be the abrupt and jarring reversal of positions that occurs near the very end of the text. Perhaps most notorious of all, there is the famous theory of "divine illumination" with which the dialogue concludes. It is worth noting, however, that as odd and as digressive as this eudaimonistic interlude may strike the present-day reader, it does not seem to strike Adeodatus as at all odd, nor does it seem out of keeping with the eudaimonistic emphasis that is such a prominent feature of Augustine's other works from roughly the same period. 3 Indeed, our passage, although easily swept aside and passed over, can do much to provide a unifying strand which ties our difficulties together; it is, indeed, a helpful prism through which we can view those difficulties in a new light. [End Page 468] 2. Some Initial Darkness And the difficulties are indeed quite real. To begin with, there is the awkward view of language that underlies the entire discussion. "Words" (verba) are "signs" (signa) (DM 2.3), and there is a fundamental distinction between a "sign" and "signifiables" (significabilia) which are signified by signs (DM 4.8). Language, on this account, is fundamentally instrumental (see, e.g., DM 9.25), for each word is a means by which one attempts to draw attention to that which the word, qua sign, somehow signifies. As Wittgenstein says in his famous gloss on Confessions I.8, In this picture of language we find the roots of the following idea, E.g. Every word has a meaning. The meaning is correlated with the word. It is the object for which the word stands... (shrink)

This concluding section applies the results of the previous part to some important thermodynamical systems. Even if time reversibility is allowed, it is shown that the flow vectors used to derive Onsager reciprocity from time translational invariance is of questionable validity. The fundamental fluctuation dissipation theorem of Callen, Welton, Green and Kubo which underpin descriptions of irreversibility, insofar as they are derived from time translational invariance, is also questioned; from Part I, they cannot be derived properly from time reversal symmetry. (...) The common view of entropy as some type of caloric fluid flow is critiqued as not conforming to the Kelvin Clausius Planck definition. An example of developing reciprocal relations to any order in the coupling indices based on the peculiar physical and defining characteristics of conductive heat is given for the steady state whenever a temperature gradient is present, free from time reversible and translation assumptions. A major challenge in the theory is to extend it to isothermal states. It is concluded that other more deterministic views mediated by authentic work anamnesis may be needed for long term coherence. (shrink)

Much of the attention of philosophy of science, history of science, and psychology in the twentieth century has focused on the nature of conceptual change. Conceptual change in science has occupied pride of place in these disciplines, as either the subject of inquiry or the source of ideas about the nature of conceptual change in other domains. There have been numerous conceptual changes in the history of science, some more radical than others. One of the most radical was the chemical (...) revolution. In the seventeenth century, chemists believed that the processes of combustion and calcination involved the absorption or release of a substance called phlogiston. On this theory, when an ore is heated with charcoal, it absorbs phlogiston to produce a metal; when a metal is burned, it releases phlogiston and leaves behind a residue, or calx. The concept of phlogiston derived from a quite complex Aristotelian/medieval structure that included three concepts central to chemical theory: sulphur, the principle of inflammability; mercury, the principle of fluidity; and salt, the principle of inertness. All material substances were believed to contain these three principles in the form of earths. The phlogiston theory held that in combustion, the sulphurous earth (phlogiston) returns to the substance from which it escaped during some earlier burning process in its history, and that in calcination the process is reversed. However, chemists also knew that a calx is heavier than the metal from which it was derived. So, the theory implies that phlogiston has a negative weight, or a positive lightness. This did not present a problem, though, because it was compatible with the Aristotelian elements of fire and air (the others being earth and water), which were not attracted towards the center of the earth. The development of the oxygen theory of combustion and calcination by Lavoisier in the late eighteenth century has been called the chemical revolution because it required replacing the whole conceptual structure with, for example, different concepts of substance and element and new concepts of oxygen and caloric. In the new system, it was no longer possible to believe in the existence of substances with negative weight. According to the oxygen theory, oxygen gas is released in combustion and absorbed in calcination. Thus calx is metal (substance) plus oxygen, rather than metal minus phlogiston. The concept of phlogiston was eliminated from the chemical lexicon. The reconceptualization of chemical phenomena that took place in the chemical revolution made possible the atomic theory of matter, which, as we know, posits quite different constituents of material substances from the principles central to the earlier conceptual structure. Just what constitutes conceptual change, how it relates to theory change, and how it relates to changes in belief continues to be a subject of much debate. Clearly, though, as the preceding example demonstrates, the three are significantly interrelated. (shrink)

I deny that the world is fundamentally causal, deriving the skepticism on non-Humean grounds from our enduring failures to find a contingent, universal principle of causality that holds true of our science. I explain the prevalence and fertility of causal notions in science by arguing that a causal character for many sciences can be recovered, when they are restricted to appropriately hospitable domains. There they conform to loose and varying collections of causal notions that form folk sciences of causation. This (...) recovery of causation exploits the same generative power of reduction relations that allows us to recover gravity as a force from Einstein's general relativity and heat as a conserved fluid, the caloric, from modern thermal physics, when each theory is restricted to appropriate domains. Causes are real in science to the same degree as caloric and gravitational forces. (shrink)

Dietary restriction (DR) is the most consistent environmental manipulation to extend lifespan. Originally thought to be caused by a reduction in caloric intake, recent evidence suggests that macronutrient intake underpins the effect of DR. The prevailing evolutionary explanations for the DR response are conceptualized under the caloric restriction paradigm, necessitating reconsideration of how or whether these evolutionary explanations fit this macronutrient perspective. In the authors’ opinion, none of the current evolutionary explanations of DR adequately explain the intricacies of (...) observed results; instead a context‐dependent combination of these theories is suggested which is likely to reflect reality. In reviewing the field, it is proposed that the ability to track the destination of different macronutrients within the body will be key to establishing the relative roles of the competing theories. Understanding the evolution of the DR response and its ecological relevance is critical to understanding variation in DR responses and their relevance outside laboratory environments. (shrink)

In his Metaphysische Anfangsgründe der Naturwissenschaft (MAN), Kant claims that chemistry is an improper, though rational science. The chemistry to which Kant confers this status is the phlogistic chemistry of, for instance, Georg Stahl. In his Opus Postumum (OP), however, Kant espouses a broadly Lavoiserian conception of chemistry. In particular, Kant endorses Antoine Lavoisier's elements, oxygen theory of combustion, and role for the caloric. As Lavoisier's lasting contribution to chemistry, according to some histories of the science, was his (...) emphasis on quantitative methods, Kant's assimilation of the chemical revolution raises the question: did Kant continue to think of chemistry as an improper, though rational, science in OP? In this paper, I answer this question affirmatively. I explain that a proper science requires a priori laws for the mathematical construction of its objects: the mere use of quantitative measurements is insufficient for the satisfaction this requirement. Further, I argue, contra Burkhard Tuschling, that in OP Kant retains a central role for mathematical construction in the foundations of proper natural science. Finally, I contend that the prominent a priori components of chemistry discussed in OP—the aether and the enumeration of the elements—do not make chemistry into a proper science. (shrink)

The thermodynamic behavior is analyzed of a single classical charged particle in thermal equilibrium with classical electromagnetic thermal radiation, while electrostatically bound by a fixed charge distribution of opposite sign. A quasistatic displacement of this system in an applied electrostatic potential is investigated. Treating the system nonrelativistically, the change in internal energy, the work done, and the change in caloric entropy are all shown to be expressible in terms of averages involving the distribution of the position coordinates alone. A (...) convenient representation for the probability distribution is shown to be the ensemble average of the absolute square value of an expansion over the eigenstates of a Schrödinger-like equation, since the heat flow is shown to vanish for each hypothetical “state.” Subject to key assumptions highlighted here, the demand that the entropy be a function of state results in statistical averages in agreement with the form in quantum statistical mechanics. Examining the very low and very high temperature situations yields Planck's and Boltzmann's constants. The blackbody radiation spectrum is then deduced. From the viewpoint of the theory explored here, the method in quantum statistical mechanics of statistically counting the “states” at thermal equilibrium by using the energy eigenvalue structure, is simply a convenient counting scheme, rather than actually representing averages involving physically discrete energy states. (shrink)

Whiteheadian concepts of life, food, "empty" and "occupied space" provide a theoretical basis to unpack an ontogenetic perspective on aging. Focusing on the so-called "Selective Optimization with Compensation " strategy, this work will explore this concept in relation to some scientific evidence in the fields of "epigenetics " and molecular nutrition. Further, the role of caloric restriction in health and longevity will be discussed as a SOC strategy, based on the metabolic theory of aging. SOC strategy applied to (...) the processes of aging, when linked with Whitehead's philosophy of organism, makes it possible for us to think about life as a selective process provided by "empty space. " A continuum within the physical field optimizes a "living society," which evolves in permanent social deficit, by means of compensation by nutritional metabolism. (shrink)